All Photos(2)
Synonym(s):
Benzo[b]thiophene, Benzothiophene, Thionaphthene
Empirical Formula (Hill Notation):
C8H6S
CAS Number:
Molecular Weight:
134.20
Beilstein:
80580
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
98%
form
solid
bp
221-222 °C (lit.)
mp
30-33 °C (lit.)
density
1.149 g/mL at 25 °C (lit.)
SMILES string
c1ccc2sccc2c1
InChI
1S/C8H6S/c1-2-4-8-7(3-1)5-6-9-8/h1-6H
InChI key
FCEHBMOGCRZNNI-UHFFFAOYSA-N
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General description
Reaction of ethyl diazoacetate with thianaphthene has been reported.
Application
Thianaphthene may be used in the preparation of 2-thianapthenylphenyllithium, via metalation by n-butyllithium.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Haiying She et al.
Journal of colloid and interface science, 518, 149-155 (2018-02-18)
An adsorbent with multiple interaction sites for the adsorption of nitrogen-containing compounds (NCCs) has been realized in a silver ion functionalized Cr3+ based metal-organic framework (Cr)-MIL-101-SO3Ag. The adsorptive denitrogenation performance of (Cr)-MIL-101-SO3Ag was evaluated in a batch adsorption system in
Reactions of ethyl diazoacetate with thianaphthene, indoles, and benzofuran.
Wenkert E, et al.
The Journal of Organic Chemistry, 42(24), 3945-3949 (1977)
Some 2-Substituted Thianaphthenes Derived from 2-Thianaphthenyllithium1.
Shirley DA and Cameron MD.
Journal of the American Chemical Society, 74(3), 664-665 (1952)
Eva Tyteca et al.
Journal of chromatography. A, 1358, 145-154 (2014-07-21)
Linear gradient programs are very frequently used in reversed phase liquid chromatography to enhance the selectivity compared to isocratic separations. Multi-linear gradient programs on the other hand are only scarcely used, despite their intrinsically larger separation power. Because the gradient-conformity
Argam Akopyan et al.
Molecules (Basel, Switzerland), 25(3) (2020-01-30)
Polyoxometalate-based ionic liquid hybrid materials with a pyridinium cation, containing Brönsted acid sites, were synthesized and used as catalysts for the oxidation of model and real diesel fuels. Keggin-type polyoxometalates with the formulae [PMo12O40]3-, [PVMo11O40]4-, [PV2Mo10O40]4-, [PW12O40]3- were used as
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