Skip to Content
Merck
CN

346152

Ethynylmagnesium bromide solution

0.5 M in THF

Synonym(s):

Acetylenemagnesium bromide, Bromoethynylmagnesium, Ethynylmagnesium bromide

Sign In to View Organizational & Contract Pricing.

Select a Size

About This Item

Linear Formula:
HC≡CMgBr
CAS Number:
4301-14-8
Molecular Weight:
129.24
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
24861376
MDL number:
MFCD00075342
Beilstein/REAXYS Number:
3600874

Key Documents

View All Documentation
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Product Name

Ethynylmagnesium bromide solution, 0.5 M in THF

InChI

1S/C2H.BrH.Mg/c1-2;;/h1H;1H;/q;;+1/p-1

SMILES string

Br[Mg]C#C

InChI key

HUGJUYPSXULVQQ-UHFFFAOYSA-M

reaction suitability

reaction type: Grignard Reaction

concentration

0.5 M in THF

density

0.94 g/mL at 25 °C

storage temp.

2-8°C

Quality Level

200

Looking for similar products? Visit Product Comparison Guide

Related Categories

Application

Ethynylmagnesium bromide solution can be used in:
  • Grafting of aliphatic polymer.
  • Synthesis of anthracene-containing species like 1,8-dichloro-10-(ethynyl)anthracene.
  • The preparation of the alkyne component in an enyne cross-metathesis leading to conjugated dienes.
  • Ethynylation of chiral α-(dibenzylamino) aldehydes.
  • The synthesis of ethynyl aziridines.
  • To prepare alkyl(triethynyl)germanes from tert-alkyltrichlorogermanes and 2-butyltrichlorogermane.
  • The preperation of a key intermediate in the total synthesis of (+)-4-demethoxydaunomycin.

General description

Ethynylmagnesium bromide solution, also known as bromoethynylmagnesium, is a grignard reagent that is commonly used in the synthesis of polymers, and unsaturated phosphonites.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2

target_organs

Respiratory system

supp_hazards

EUH019

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

-20.2 °F

flash_point_c

-29 °C

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
This item has

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
SDBB5763
SHBS6468
STBL4080
SHBR7549
SHBR4981

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Highly heat resistant and thermo-oxidatively stable borosilane alkynyl hybrid polymers
Hua Z,et al.
Royal Society of Chemistry Advances, 5, 12161-12167 (2015)
An enantioselective formal synthesis of 4-demethoxydaunomycin using the catalytic asymmetric ring opening reaction of meso-epoxide with p-anisidine
Sekine A, et al.
Tetrahedron, 58(1), 75-82 (2002)
Tandem enyne metathesis and Claisen rearrangement: a versatile approach to conjugated dienes of variable substitution patterns
Clark DA, et al.
Journal of the American Chemical Society, 128(49), 15632-15636 (2006)
Improved Access to 1, 8-Dichloro-10-(ethynyl) anthracene: A Useful Building Block for (Semi-) rigid Organic Frameworks
Jan-Hendrik L,et al.
Synthesis, 50, 2009-2018 (2018)
Daniel A Clark et al.
Journal of the American Chemical Society, 128(49), 15632-15636 (2006-12-07)
To extend the versatility of the ruthenium carbene-promoted enyne metathesis, it was combined with an Ireland ester enolate Claisen rearrangement. This reaction sequence provided conjugated dienes of higher substitution pattern than that obtained through a cross-enyne metathesis alone. The Ireland-Claisen
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service