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345229

Sigma-Aldrich

Dichloro(N,N,N′,N′-tetramethylethylenediamine)palladium(II)

99%

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Synonym(s):
NSC 241246, Tetramethylethylenediaminepalladium dichloride, [1,2-Bis(dimethylamino)ethane]dichloropalladium
Linear Formula:
[(CH3)2NCH2CH2N(CH3)2]PdCl2
CAS Number:
Molecular Weight:
293.53
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:

Assay

99%

form

powder

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

mp

245 °C (dec.) (lit.)

SMILES string

Cl[Pd]Cl.CN(C)CCN(C)C

InChI

1S/C6H16N2.2ClH.Pd/c1-7(2)5-6-8(3)4;;;/h5-6H2,1-4H3;2*1H;/q;;;+2/p-2

InChI key

FJOUSQLMIDWVAY-UHFFFAOYSA-L

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Application

Catalyst for:
  • Cross-coupling reactions
  • Catalytic reduction reactions
  • Preparation of silyl ethers via reaction of silicon-hydrogen bond with alcohols
  • Oxidative carbonylation reactions

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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