34075
Methyl 2,4-dibromobutyrate
≥97.0% (GC)
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About This Item
Linear Formula:
BrCH2CH2CHBrCOOCH3
CAS Number:
Molecular Weight:
259.92
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1757129
Assay:
≥97.0% (GC)
Form:
solid
InChI
1S/C5H8Br2O2/c1-9-5(8)4(7)2-3-6/h4H,2-3H2,1H3
SMILES string
COC(=O)C(Br)CCBr
InChI key
DQHIGEQXJBMKKY-UHFFFAOYSA-N
assay
≥97.0% (GC)
form
solid
density
1.840 g/mL at 20 °C (lit.)
functional group
bromo, ester
storage temp.
2-8°C
Quality Level
Related Categories
General description
Methyl 2,4-dibromobutyrate reacts with sodium azide in dimethylformamide to yield 2-azido-4-bromobutyrate.
Application
Methyl 2,4-dibromobutyrate was used in the preparation of stereoisomers of azetidine-2-carboxylic amide derivative.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Observations on the chemistry of. alpha.-azido ester. Efficient synthesis of a potently sweet homoserine-dihydrochalcone conjugate.
DuBois GE, et al.
The Journal of Organic Chemistry, 47(7), 1319-1323 (1982)
Synthesis and X-ray analysis of 1-((1S)-phenylethyl)-azetidine-(2R)-piperidinamide.
De Gelder R, et al.
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