33820
Dibenzyl sulfide
≥95.0% (HPLC)
Synonym(s):
Benzyl sulfide
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About This Item
Linear Formula:
(C6H5CH2)2S
CAS Number:
Molecular Weight:
214.33
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-703-6
Beilstein/REAXYS Number:
1911157
MDL number:
Product Name
Dibenzyl sulfide, ≥95.0% (HPLC)
Quality Level
functional group
thioether
phenyl
InChI key
LUFPJJNWMYZRQE-UHFFFAOYSA-N
InChI
1S/C14H14S/c1-3-7-13(8-4-1)11-15-12-14-9-5-2-6-10-14/h1-10H,11-12H2
SMILES string
C(SCc1ccccc1)c2ccccc2
assay
≥95.0% (HPLC)
form
solid
mp
44-47 °C (lit.)
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General description
Sulfur K-edge XANES spectra of dibenzyl sulfide has been measured. Adsorption modes of dibenzyl disulphide on bare and iron-coated silver in 0.5M HCl was studied by surface-enhanced Raman scattering (SERS) spectroscopy. Dibenzyl sulfide undergoes oxidation to dibenzyl sulfoxide by SiO2-HNO3/KBr.
Storage Class
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Vered Heleg-Shabtai et al.
Advances in experimental medicine and biology, 733, 53-61 (2011-11-22)
The improvements in Raman instrumentation have led to the development of -portable, simple to operate, Raman instruments that can be used for on-site analysis of substances relevant for homeland security purposes such as chemical and biological warfare and explosives materials.Raman
B Lei et al.
Journal of bacteriology, 178(19), 5699-5705 (1996-10-01)
The oxidation of dibenzothiophene to dibenzothiophene sulfone has been linked to the enzyme encoded by the sox/dszC gene from Rhodococcus sp. strain IGTS8 (S. A. Denome, C. Oldfield, L. J. Nash, and K. D. Young, J. Bacteriol. 176:6707-6717, 1994; C.
Jonathan D Van Hamme et al.
Applied and environmental microbiology, 69(2), 1320-1324 (2003-02-07)
Microbial metabolism of organosulfur compounds is of interest in the petroleum industry for in-field viscosity reduction and desulfurization. Here, dibenzyl sulfide (DBS) metabolism in white rot fungi was studied. Trametes trogii UAMH 8156, Trametes hirsuta UAMH 8165, Phanerochaete chrysosporium ATCC
Robert Beck et al.
Dalton transactions (Cambridge, England : 2003), (37)(37), 4981-4983 (2008-09-20)
C-H activation through the coordination of a benzyl sulfide anchoring group with a C-S bond cleavage at a Co(v) center constitutes a regiospecific access to four- and five-membered metallacycles under mild conditions.
Chemo and homoselective catalytic oxidation of sulfides to sulfoxides with supported nitric acid on silica gel and poly vinyl pyrrolidone (PVP) catalyzed by KBr and/or NaBr.
Zolfigol MA, et al.
Catalysis Communications, 9(8), 1739-1744 (2008)
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