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337773

Sigma-Aldrich

Chlorodiisopropylphosphine

96%

Synonym(s):

Diisopropylphosphine chloride

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About This Item

Linear Formula:
[(CH3)2CH]2PCl
CAS Number:
40244-90-4
Molecular Weight:
152.60
MDL number:
MFCD00015027
UNSPSC Code:
12352001
PubChem Substance ID:
24860498
NACRES:
NA.22

Quality Level

100

Assay

96%

form

liquid

reaction suitability

reagent type: ligand
reaction type: Arylations

refractive index

n20/D 1.475 (lit.)

bp

69 °C/33 mmHg (lit.)

density

0.959 g/mL at 25 °C (lit.)

functional group

phosphine

SMILES string

CC(C)P(Cl)C(C)C

InChI

1S/C6H14ClP/c1-5(2)8(7)6(3)4/h5-6H,1-4H3

InChI key

JZPDBTOWHLZQFC-UHFFFAOYSA-N

Related Categories

Application

Chlorodiisopropylphosphine can be used:
  • To synthesize p-styryldiisopropylphosphine by reacting with 4-chlorostyrene via Grignard reaction.
  • As a phosphination reagent in combination with [Cp2Zr(1-butene)(DMAP)] (Cp=cyclopentadienyl; DMAP= 4-(dimethylamino)pyridine)) for the zirconophosphination of alkynes to form zirconoalkenylphosphines.
  • A luminescent mixed-donor platinum POCN pincer complex via cyclometalation process.

Pictograms

FlameCorrosion
GHS02,GHS05

Signal Word

Danger

Hazard Statements

H225,H314

Hazard Classifications

Flam. Liq. 2 - Skin Corr. 1B

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

监管及禁止进口产品

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Metallophosphination of alkynes: efficient synthesis of ?-functionalized alkenylphosphines.
Xi C, et al.
Organometallics, 26(4), 1084-1088 (2007)
Synthesis, characterization and use of reactive polymers with diisopropylphenylphosphine groups.
Licea-Claverie A, et al.
Polymer Bull., 39(5), 551-557 (1997)
A luminescent Pt-POCN pincer complex via direct cyclometalation.
Lavelle K B, et al.
Journal of Organometallic Chemistry, 785, 100-105 (2015)

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