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Sigma-Aldrich

Dichloro(1,5-cyclooctadiene)ruthenium(II), polymer

greener alternative

95%

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Synonym(s):
(1,5-Cyclooctadiene)ruthenium(II) chloride, Ruthenium(II) chloride 1,5-cyclooctadiene complex
Linear Formula:
[Ru(COD)Cl2]n
CAS Number:
50982-12-2
Molecular Weight:
280.16 (as monomer)
UNSPSC Code:
12352200
NACRES:
NA.22

Assay

95%

reaction suitability

core: ruthenium
reaction type: solution phase peptide synthesis
reagent type: catalyst

greener alternative product characteristics

Catalysis
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, Aligned

InChI

1S/C8H12.2ClH.Ru/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2

InChI key

DMRVBCXRFYZCPR-UHFFFAOYSA-L

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Versatile Ru catalyst precursor. Used with IMes to catalyze the dehydrogenative coupling of alcohols and amines to form amide bonds.
Versatile ruthenium catalyst precursor. Used with NHC ligand to catalyze greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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