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Merck
CN

334545

Potassium gold(III) chloride

98%

Synonym(s):

Potassium tetrachloroaurate(III), Gold potassium chloride

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About This Item

Linear Formula:
KAuCl4
CAS Number:
Molecular Weight:
377.88
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
237-190-1
MDL number:
Assay:
98%
Form:
powder
Solubility:
H2O: soluble
alcohol: soluble
ethanol: soluble
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Product Name

Potassium gold(III) chloride, 98%

InChI key

JMONCQYBAMKVQQ-UHFFFAOYSA-J

InChI

1S/Au.4ClH.K/h;4*1H;/q+3;;;;;+1/p-4

SMILES string

[K+].Cl[Au-](Cl)(Cl)Cl

assay

98%

form

powder

reaction suitability

core: potassium

solubility

H2O: soluble
alcohol: soluble
ethanol: soluble

Quality Level

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Application

Key raw material for synthesis of new gold(III) dithiolate complexes for luminescence studies or possible uses as photosensitizers or photocatalysts.

General description

The yellow crystals of potassium gold chloride are soluble in water. 1,2

signalword

Warning

pictograms

Exclamation mark

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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M. Adnan Mansour et al.
Inorganic chemistry, 37(18), 4625-4632 (2001-10-24)
Two Au(III) dithiolate complexes, [Au(dbbpy)(tdt)]PF(6) and Au(eta(2)-C,N-ppy)(tdt), (dbbpy = 4,4'-di-tert-butyl-2,2'-bipyridine; tdt = 3,4-toluenedithiolate; ppy = C-deprotonated 2-phenylpyridine), have been prepared and structurally characterized by X-ray crystallography. The complexes have low-energy absorption bands that exhibit mild solvatochromism (lambda(max) = 444 nm
Ja-an Annie Ho et al.
Analytical chemistry, 84(7), 3246-3253 (2012-03-01)
In this paper, we describe a simple one-pot method, employing l-3,4-dihydroxyphenylalanine (L-DOPA) as a reducing/capping reagent, for the synthesis of fluorescent gold nanoclusters (AuNCs). Within a short reaction time of 15 min (excluding the time required for purification), this strategy
Xianqing Tian et al.
Talanta, 93, 79-85 (2012-04-10)
Graphene decorated with gold nanoparticles (AuNPs-β-CD-Gra) has been synthesized by in situ thermal reduction of graphene oxide and HAuCl(4) with β-cyclodextrin (β-CD) under alkaline condition. The AuNPs-β-CD-Gra product was well characterized by infrared spectroscopy, X-ray powder diffraction, scanning electron microscopy
S Veeraapandian et al.
Journal of biomedical nanotechnology, 8(1), 140-148 (2012-04-21)
Escherichia coli is used for eco-friendly extra cellular synthesis of metallic silver and gold nanoparticles. This is achieved by reducing AgNO3 and HAuCl4 solutions respectively under ambient conditions by using the extra cellular protein produced by the microorganism. The proteins
Sergey S Zalesskiy et al.
Journal of the American Chemical Society, 135(9), 3550-3559 (2013-01-02)
Soluble gold precatalysts, aimed for homogeneous catalysis, under certain conditions may form nanoparticles, which dramatically change the mechanism and initiate different chemistry. The present study addresses the question of designing gold catalysts, taking into account possible interconversions and contamination at

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