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Merck
CN

328332

Dimethylphosphinic chloride

97%

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About This Item

Linear Formula:
(CH3)2P(O)Cl
CAS Number:
Molecular Weight:
112.50
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
214-187-3
MDL number:
Assay:
97%
Form:
solid
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InChI key

CVNMBKFJYRAHPO-UHFFFAOYSA-N

InChI

1S/C2H6ClOP/c1-5(2,3)4/h1-2H3

SMILES string

CP(C)(Cl)=O

assay

97%

form

solid

bp

204 °C (lit.)

mp

65-71 °C (lit.)

functional group

phosphine oxide

General description

Kinetics of pyridinolyses of dimethylphosphinic chloride in acetonitrile was studied. Kinetics and mechanism of the reaction of dimethyl phosphinic chloride with anilines in acetonitrile was studied.

Application

Dimethylphosphinic chloride was used in preparation of dimethyl-ethynylphosphine oxide.

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

监管及禁止进口产品
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Pyridinolysis of Diethyl Phosphinic Chloride in Acetonitrile.
Dey NK, et al.
Bull. Korean Chem. Soc., 32(2), 709-712 (2011)
Dialkylethynylphosphine oxides; synthesis and reactions.
Hagens W, et al.
Rec. Trav. Chim., 88(1), 71-85 (1969)
Kinetics and mechanism of the aminolysis of dimethyl and methyl phenyl phosphinic chlorides with anilines.
Dey NK, et al.
Journal of Physical Organic Chemistry, 22(5), 425-430 (2009)

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