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Key Documents

Safety Information

327115

Sigma-Aldrich

o-Toluidine hydrochloride

98%

Synonym(s):

2-Methylaniline hydrochloride

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About This Item

Linear Formula:
CH3C6H4NH2 · HCl
CAS Number:
Molecular Weight:
143.61
Beilstein:
3558629
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:

Assay

98%

mp

215-217 °C (lit.)

SMILES string

Cl.Cc1ccccc1N

InChI

1S/C7H9N.ClH/c1-6-4-2-3-5-7(6)8;/h2-5H,8H2,1H3;1H

InChI key

OGVXWEOZQMAAIM-UHFFFAOYSA-N

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General description

o-Toluidine hydrochloride is a demonstrated animal carcinogen.

Application

o-Toluidine hydrochloride was used in preparation of 9,9-bis(3-methyl-4-aminophenyl)fluorine.

Pictograms

Health hazardExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Carc. 1B

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

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M Elwell
Toxicity report series, 44, 1-C8-1-C8 (2002-07-16)
o-Nitrotoluene and o-toluidine hydrochloride are structurally related chemicals that are suspected and demonstrated animal carcinogens, respectively. The metabolic potential of the gastrointestinal flora is considered an important factor in o-nitrotoluene-induced toxicity and involves the reduction of the nitro group to
Ortho alkyl substituents effect on solubility and thermal properties of fluorenyl cardo polyimides.
Hu Z, et al.
Polymer, 46(14), 5278-5283 (2005)
Tania Carreón et al.
Occupational and environmental medicine, 67(5), 348-350 (2009-11-04)
In 1991, the US National Institute for Occupational Safety and Health (NIOSH) reported an increased bladder cancer risk in a cohort of 1749 workers potentially exposed to o-toluidine and aniline at a chemical manufacturing plant. As additional information showed that
An o-toluidine method for body-fluid glucose determination.
Kurt M Dubowski
Clinical chemistry, 54(11), 1919-1920 (2008-10-30)
Jin Anotai et al.
Journal of hazardous materials, 196, 395-401 (2011-10-19)
A Box-Behnken design (BBD) statistical experimental design was used to investigate the degradation of o-toluidine by the electro-Fenton process. This method can be used to determine the optimal conditions in multivariable systems. Fe(2+) concentration (0.2-1.0mM), H(2)O(2) concentration (1-5mM), pH (2-4)

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