305316
(Ethoxycarbonylmethyl)triphenylphosphonium chloride
technical grade, 80%
Synonym(s):
(2-Ethoxy-2-oxoethyl)triphenylphosphonium chloride
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About This Item
Linear Formula:
CH3CH2OCOCH2P(Cl)(C6H5)3
CAS Number:
Molecular Weight:
384.84
Beilstein:
3924139
EC Number:
MDL number:
UNSPSC Code:
12352000
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grade
technical grade
Assay
80%
mp
120-123 °C (lit.)
SMILES string
[Cl-].CCOC(=O)C[P+](c1ccccc1)(c2ccccc2)c3ccccc3
InChI
1S/C22H22O2P.ClH/c1-2-24-22(23)18-25(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h3-17H,2,18H2,1H3;1H/q+1;/p-1
InChI key
DJGHVEPNEJKZBF-UHFFFAOYSA-M
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Application
Reactant for:
- Preparation of disubstituted tetrahydrofurans as selective serotonin re-uptake inhibitors for the treatment of depression
- Ring-opening reactions with Wittig reagents
- Enantioselective total synthesis of the phytotoxic lactone herbarumin III via Keck′s asymmetric allylation and Sharpless epoxidation
- Synthesis of fluorobenzofurans via microwave-assisted tandem intramolecular Wittig and Claisen rearrangement reactions
- Preparation of phosphonium derivatives of coumarin
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