304026
Sodium cyclopentadienylide
2.4 M in THF
Synonym(s):
Cyclopentadienylsodium solution
About This Item
form
liquid
Quality Level
reaction suitability
reagent type: ligand
concentration
2.4 M in THF
density
0.938 g/mL at 25 °C
SMILES string
[Na]C1C=CC=C1
InChI
1S/C5H5.Na/c1-2-4-5-3-1;/h1-5H;
InChI key
PDTZVKVFAJGNRV-UHFFFAOYSA-N
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Application
- Ruthenocene and fullerene molecular hybrid, Ru(η5- C60Me5)( η5-C5H5) (bucky ruthenocene).
- Allyl-substituted cyclopentadiene by palladium-catalyzed allylic alkylation.
- Bis(cyclopentadienyl)zirconium dichloride which is used as a catalyst in the synthesis of bis(indolyl)methanes and alkylation of heteroaryls.
- Cp-cobaltacycles from diphenylphosphinoalkynes and CoCl(PPh3)3.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
Target Organs
Central nervous system, Respiratory system
Supplementary Hazards
WGK
WGK 3
Flash Point(F)
1.4 °F
Flash Point(C)
-17 °C
Personal Protective Equipment
Regulatory Information
Certificates of Analysis (COA)
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