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γ,γ-Dimethylallyl chloride, 1,1-Dimethyl-3-chloro-1-propene, 1-Chloro-3-methyl-2-butene, 2-Methyl-4-chloro-2-butene, 3,3-Dimethylallyl chloride, 3-Methyl-2-butenyl chloride, 3-Methylcrotyl chloride, 4-Chloro-2-methyl-2-butene
(CH3)2C=CHCH2Cl
Recommended Products
Quality Level
Assay
95%
form
liquid
refractive index
n20/D 1.4488 (lit.)
bp
58-59 °C/120 mmHg (lit.)
density
0.928 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
C\C(C)=C\CCl
InChI
1S/C5H9Cl/c1-5(2)3-4-6/h3H,4H2,1-2H3
InChI key
JKXQKGNGJVZKFA-UHFFFAOYSA-N
Related Categories
General description
Kinetics of gas-phase reactions of ozone with 1-chloro-3-methyl-2-butene was studied. Reaction of 1-chloro-3-methyl-2-butene with potassium iodide in acetone and sodium ethoxide in ethanol was studied.
Application
1-Chloro-3-methyl-2-butene was used in total synthesis of geraniol.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
55.4 °F
Flash Point(C)
13 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
危险化学品
Certificates of Analysis (COA)
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The influence of orbital asymmetry on the kinetics of the gas-phase reactions of ozone with unsaturated compounds.
Physical Chemistry Chemical Physics, 2(3), 323-328 (2000)
Allylic Chlorides. VIII. 1-Chloro-3-methyl-2-butene.
Journal of the American Chemical Society, 71(5), 1679-1680 (1949)
Allylic Rearrangement in the Reactions of 1-Chloro-3-methyl-2-butene; an Attempt at Total Synthesis of Geraniol.
Journal of the American Chemical Society, 76(21), 5403-5405 (1954)
Chemistry, an Asian journal, 15(11), 1701-1708 (2020-04-16)
Alkylation of homofullerene [6,6]-C60 (CF2 )2- dianion with the set of alkyl halides, RX, was established to demonstrate an effect of RX nature on the conversion, product composition, and regioselectivity. The respective C60 (CF2 )RH, C60 (CF2 )R2 and C60
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