303046
2′-Hydroxy-6′-methoxyacetophenone
97%
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About This Item
Linear Formula:
HOC6H3(OCH3)COCH3
CAS Number:
Molecular Weight:
166.17
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
211-872-9
MDL number:
Product Name
2′-Hydroxy-6′-methoxyacetophenone, 97%
InChI key
UENLHUMCIOWYQN-UHFFFAOYSA-N
InChI
1S/C9H10O3/c1-6(10)9-7(11)4-3-5-8(9)12-2/h3-5,11H,1-2H3
SMILES string
COc1cccc(O)c1C(C)=O
assay
97%
bp
141 °C/16 mmHg (lit.)
mp
58-60 °C (lit.)
General description
An organometallic synthetic route to 2′-hydroxy-6′-methoxyacetophenone was reported.
Application
2′-Hydroxy-6′-methoxyacetophenone was used as starting material in the synthesis of 5-methoxyflavaone. It was also used in synthesis of 5,6-dihydroxyflavone.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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An Organometallic Route to 2'-Hydroxy-6'-methoxy-acetophenone.
Mincheva Z, et al.
Synthetic Communications, 25(2), 149-155 (1995)
A convenient large-scale synthesis of 5-methoxyflavone and its application to analog preparation
Ares JJ, et al.
The Journal of Organic Chemistry, 58(27), 7903-7905 (1993)
204. The synthesis of 5: 6-dihydroxyflavone and the structure of primetin.
Baker W.
Journal of the Chemical Society, 956-961 (1939)
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