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301957

Sigma-Aldrich

10-Camphorsulfonyl chloride

98%

Synonym(s):

Camphor-10-sulfonic acid chloride

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About This Item

Empirical Formula (Hill Notation):
C10H15ClO3S
CAS Number:
Molecular Weight:
250.74
Beilstein:
3205975
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

98%

form

powder

mp

66-68 °C (lit.)

SMILES string

CC1(C)[C@H]2CC[C@]1(CS(Cl)(=O)=O)C(=O)C2

InChI

1S/C10H15ClO3S/c1-9(2)7-3-4-10(9,8(12)5-7)6-15(11,13)14/h7H,3-6H2,1-2H3/t7-,10-/m0/s1

InChI key

BGABKEVTHIJBIW-XVKPBYJWSA-N

Application

10-Camphorsulfonyl chloride was used in preparation of 1,2-bis(hydroxycamphorsulfonamido)cyclohexenes and 10-mercaptoisoborneol.

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

新产品

Certificates of Analysis (COA)

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Highly enantioselective addition of dialkylzinc reagents to ketones promoted by titanium tetraisopropoxide.
Yus M, et al.
Tetrahedron Asymmetry, 13(21), 2291-2293 (2002)
Asymmetric synthesis of nearly optically pure atrolactic acid methyl ether.
Eliel EL and Frazee WJ.
The Journal of Organic Chemistry, 44(20), 3598-3599 (1979)

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