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Key Documents

Safety Information

299065

Sigma-Aldrich

N′-tert-Butyl-N,N-dimethylformamidine

97%

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About This Item

Linear Formula:
HC[=NC(CH3)3]N(CH3)2
CAS Number:
Molecular Weight:
128.22
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

97%

refractive index

n20/D 1.445 (lit.)

bp

137-140 °C (lit.)

density

0.815 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

CN(C)\C=N\C(C)(C)C

InChI

1S/C7H16N2/c1-7(2,3)8-6-9(4)5/h6H,1-5H3/b8-6+

InChI key

PHNRCFCIKPZSFS-SOFGYWHQSA-N

General description

Enamidine intermediates derived from N′-tert-butyl-N,N-dimethylformamidine were converted into homologated secondary amines, aldehydes or ketones. Formamidines were reviewed as precursors to α-amino carbanions.

Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Flam. Liq. 3 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

93.2 °F - closed cup

Flash Point(C)

34 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品

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Journal of the American Chemical Society, 104, 877-877 (1982)
Aldrichimica Acta, 18, 59-59 (1985)

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