298883
(S)-(−)-4-Isopropyl-2-oxazolidinone
99%
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About This Item
Empirical Formula (Hill Notation):
C6H11NO2
CAS Number:
Molecular Weight:
129.16
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3588198
Product Name
(S)-(−)-4-Isopropyl-2-oxazolidinone, 99%
InChI
1S/C6H11NO2/c1-4(2)5-3-9-6(8)7-5/h4-5H,3H2,1-2H3,(H,7,8)/t5-/m1/s1
SMILES string
CC(C)[C@H]1COC(=O)N1
InChI key
YBUPWRYTXGAWJX-RXMQYKEDSA-N
assay
99%
form
solid
optical activity
[α]20/D −18°, c = 6 in ethanol
optical purity
ee: 98% (GLC)
mp
70-73 °C (lit.)
Quality Level
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Application
Reagent employed as a chiral ligand in dirhodium(II) complexes and as a chiral auxiliary in aldol addition reactions. Versatile chiral auxiliary for asymmetric synthesis. For a recent review, see Aldrichimica Acta.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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Find documentation for the products that you have recently purchased in the Document Library.
The Journal of Organic Chemistry, 58, 5107-5107 (1993)
Journal of the American Chemical Society, 115, 9968-9968 (1993)
Ager, D.J., et al.
Aldrichimica Acta, 30, 3-3 (1997)
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