298190
Cerium(III) chloride
AnhydroBeads™, −10 mesh, 99.9%
Synonym(s):
Cerium trichloride, Cerous chloride
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About This Item
Empirical Formula (Hill Notation):
CeCl3
CAS Number:
Molecular Weight:
246.48
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
232-227-8
MDL number:
Assay:
99.9%
Grade:
synthesis grade
grade
synthesis grade
product line
AnhydroBeads™
assay
99.9%
reaction suitability
core: cerium, reagent type: catalyst
impurities
≤1500.0 ppm Trace Rare Earth Analysis
particle size
−10 mesh
mp
848 °C (lit.)
density
3.97 g/mL at 25 °C (lit.)
SMILES string
Cl[Ce](Cl)Cl
InChI
1S/Ce.3ClH/h;3*1H/q+3;;;/p-3
InChI key
VYLVYHXQOHJDJL-UHFFFAOYSA-K
Application
When added to nitrile aldol reactions, diastereoselectivity is enhanced, providing high yields of β-hydroxynitriles.
Legal Information
AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC
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Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1C
Storage Class
8B - Non-combustible corrosive hazardous materials
wgk
WGK 2
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Xiaoming Tao et al.
Organic letters, 15(1), 72-75 (2012-12-25)
Dynamic kinetic resolution of various α-amido-β-keto phosphonates via asymmetric hydrogenation proceeded efficiently to give the corresponding β-hydroxy-α-amido phosphonates in high diastereo- and enantioselectivities (up to 99:1 syn/anti, 99.8% ee). The addition of catalytic amounts of CeCl(3)·7H(2)O is necessary to achieve
Na Li et al.
Environmental toxicology, 28(6), 349-358 (2011-06-10)
To investigate the molecular mechanism of inflammatory response in the mouse liver caused by exposure to CeCl₃, we measured the liver indices, and cerium content, evaluated the liver histopathological section, detected serum biochemical parameters of liver function, and the immunoglobulin
Giuseppe Bartoli et al.
Organic & biomolecular chemistry, 8(15), 3509-3517 (2010-06-10)
The occurrence of unsaturated systems in natural products combined with the mildness and the wide range of applicability of CeCl(3) promoted methodologies suggest several potential future synthetic applications within the field of total synthesis of biologically active molecules. On this
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 298190-50G | 04061826657119 |