29512
(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine]
≥97%, optical purity ee: ≥99%
Synonym(s):
(R)-3,5-t-Bu-4-MeO-MeOBIPHEP, (R)-[6,6′-Dimethoxy(1,1′-biphenyl)-2,2′-diyl]bis{bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphine}, SL-A109-1
About This Item
Assay
≥97%
optical purity
ee: ≥99%
InChI
1S/C74H104O6P2/c1-67(2,3)49-37-45(38-50(63(49)77-27)68(4,5)6)81(46-39-51(69(7,8)9)64(78-28)52(40-46)70(10,11)12)59-35-31-33-57(75-25)61(59)62-58(76-26)34-32-36-60(62)82(47-41-53(71(13,14)15)65(79-29)54(42-47)72(16,17)18)48-43-55(73(19,20)21)66(80-30)56(44-48)74(22,23)24/h31-44H,1-30H3
InChI key
JSSIQFXOSWLAGA-UHFFFAOYSA-N
General description
Application
- Asymmetrical conjugate addition of arylboronic acids to maleimides and enones catalyzed by rhodium complexes
- Intramolecular ketone hydroacylation
- Desymmetrization through enantioselective C-C bond activation and ring expansion of allenyl cyclobutanols
- Hydroamination of bicyclic alkenes and dienes with anilines
- 1,4-addition/asymmetric protonation of amino acrylates
Packaging
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Articles
Solvias MeOBIPHEP Ligands: State-of-the-art atropisomeric MeOBIPHEP ligands, also referred to as MeO-BIPHEP, originally developed by Roche, have an extraordinarily broad performance profile for many synthetic applications due to their modular ligand design.
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service