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About This Item
Empirical Formula (Hill Notation):
BCl3
CAS Number:
Molecular Weight:
117.17
EC Number:
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:
Recommended Products
vapor density
4.05 (vs air)
Quality Level
vapor pressure
1128 mmHg ( 20 °C)
2815 mmHg ( 55 °C)
Assay
99.9%
reaction suitability
reagent type: catalyst
core: boron
bp
12.5 °C (lit.)
mp
−107 °C (lit.)
SMILES string
ClB(Cl)Cl
InChI
1S/BCl3/c2-1(3)4
InChI key
FAQYAMRNWDIXMY-UHFFFAOYSA-N
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Application
Used in the high-temperature synthesis of layered graphite-like material with p-type semiconductor properties. Highly acidic boronated aluminas derived from BCl3 promote regio- and diastereoselectivity in Diels-Alder reactions.
Recommended products
Monel control valve Z146978 or Monel gas regulator Z562483 is recommended.
recommended
Product No.
Description
Pricing
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Press. Gas Compr. Gas - Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
Supplementary Hazards
Storage Class Code
2A - Gases
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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McGinnis, M.B. et al.
The Journal of Organic Chemistry, 61, 3496-3496 (1996)
Kawaguchi, M. et al.
Chemistry of Materials, 8, 1197-1197 (1996)
Novel polyhydroxylated cyclic nitrones and N-hydroxypyrrolidines through BCl3-mediated deprotection.
Stéphanie Desvergnes et al.
Organic letters, 10(14), 2967-2970 (2008-06-24)
A general method to prepare a new class of carbohydrate-derived, enantiomerically pure polyhydroxypyrroline N-oxides from their alkoxy (protected) derivatives is presented. Boron trichloride is shown to cleave efficiently benzyl ethers and ketals without affecting the imine N-oxide functionality of nitrones.
Lei Zhang et al.
Journal of combinatorial chemistry, 8(3), 361-367 (2006-05-09)
A novel and efficient microwave-assisted, BCl(3) mediated coupling reaction to synthesize o-(hydroxyaryl)(aryl)methanone structures from phenols and acyl chlorides is described. This reaction was further incorporated into a two-step synthesis of biologically interesting xanthones.
Stephen Sproules et al.
Inorganic chemistry, 50(10), 4503-4514 (2011-04-19)
Sky-blue Tp*WOCl(2) has been synthesized from the high-yielding reaction of Tp*WO(2)Cl with boron trichloride in refluxing toluene. Dark-red Tp*WOI(2) was prepared via thermal decarbonylation followed by aerial oxidation of Tp*WI(CO)(3) in acetonitrile. From these precursors, an extensive series of mononuclear
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