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Key Documents

Safety Information

294012

Sigma-Aldrich

tert-Butyl methyl sulfide

97%

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About This Item

Linear Formula:
(CH3)3CSCH3
CAS Number:
Molecular Weight:
104.21
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:

Assay

97%

refractive index

n20/D 1.44 (lit.)

bp

101-102 °C (lit.)

density

0.826 g/mL at 25 °C (lit.)

SMILES string

CSC(C)(C)C

InChI

1S/C5H12S/c1-5(2,3)6-4/h1-4H3

InChI key

CJFVCTVYZFTORU-UHFFFAOYSA-N

General description

Alloxazine-cyclodextrin conjugate catalyzed enantioselective oxidation of tert-butyl methyl sulfide has been reported.

Pictograms

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Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

24.8 °F - closed cup

Flash Point(C)

-4 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Viktor Mojr et al.
Organic & biomolecular chemistry, 9(21), 7318-7326 (2011-09-01)
Four structurally different alloxazine-cyclodextrin conjugates were prepared and tested as catalysts for the enantioselective oxidation of prochiral sulfides to sulfoxides by hydrogen peroxide in aqueous solutions. The alloxazinium unit was appended to the primary face of α- and β-cyclodextrins via

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