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Merck
CN

287830

Tri(p-tolyl)phosphine

98%, solid

Synonym(s):

TPTP

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About This Item

Linear Formula:
(CH3C6H4)3P
CAS Number:
1038-95-5
Molecular Weight:
304.37
NACRES:
NA.22
PubChem Substance ID:
24857296
UNSPSC Code:
12352002
EC Number:
213-863-5
MDL number:
MFCD00008542
Beilstein/REAXYS Number:
651045

Key Documents

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Product Name

Tri(p-tolyl)phosphine, 98%

assay

98%

form

solid

SMILES string

Cc1ccc(cc1)P(c2ccc(C)cc2)c3ccc(C)cc3

InChI key

WXAZIUYTQHYBFW-UHFFFAOYSA-N

InChI

1S/C21H21P/c1-16-4-10-19(11-5-16)22(20-12-6-17(2)7-13-20)21-14-8-18(3)9-15-21/h4-15H,1-3H3

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings

mp

144-148 °C (lit.)

functional group

phosphine

Quality Level

100

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Related Categories

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
11708CH
10420HW
11306AG
07618HF
06520AB

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Mohammad Shabbir Hasan et al.
Human genomics, 9, 20-20 (2015-08-20)
Insertion and deletion (indel), a common form of genetic variation, has been shown to cause or contribute to human genetic diseases and cancer. With the advance of next-generation sequencing technology, many indel calling tools have been developed; however, evaluation and
Jingna Si et al.
International journal of molecular sciences, 16(11), 26303-26317 (2015-11-06)
Proteins and RNA interaction have vital roles in many cellular processes such as protein synthesis, sequence encoding, RNA transfer, and gene regulation at the transcriptional and post-transcriptional levels. Approximately 6%-8% of all proteins are RNA-binding proteins (RBPs). Distinguishing these RBPs
Adelaide E Clark et al.
Chemosphere, 137, 33-44 (2015-05-20)
An analytical method has been developed for the pressurized liquid extraction (PLE) of a wide range of semi-volatile organic compounds (SVOCs) from atmospheric particulate matter. Approximately 130 SVOCs from eight compound classes were selected as molecular markers of (1) agricultural
Xiaoqing Wang et al.
Chemosphere, 226, 159-165 (2019-03-31)
Organophosphate flame retardants (OPFRs) have been reported to induce cytotoxicity in a structure-dependent manner. The toxic effects may be due to the damage of biomembrane integrity and/or the interference of membrane signal pathway. In this study, the damages of fifteen
Katherine A Parrish et al.
Physical chemistry chemical physics : PCCP, 21(4), 1689-1699 (2018-09-28)
This study examined the solution-phase exchange reactions of triphenylphosphine (PPh3) ligands on Au8L72+ (L = PPh3) gold clusters with three different tolyl ligands using electrospray ionization mass spectrometry to provide insight into how steric differences in the phosphines influence the

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Catalyst Screening with Catalexis

The Catalexis platform enhances catalysis by digitally optimizing catalyst selection to identify the most effective phosphine ligands for cross-coupling reactions.

Catalexis 催化剂筛选

Catalexis平台通过数字化优化催化剂筛选，识别出交叉偶联反应最有效的膦配体，从而增强催化作用。

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