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Merck
CN

283096

tert-Amyl methyl ether

97%

Synonym(s):

1,1-Dimethylpropyl methyl ether, Methyl 2-methyl-2-butyl ether, Methyl tert-pentyl ether, TAME

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About This Item

Linear Formula:
C2H5C(CH3)2OCH3
CAS Number:
994-05-8
Molecular Weight:
102.17
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24857082
EC Number:
213-611-4
Beilstein/REAXYS Number:
1731452
MDL number:
MFCD00010186

Key Documents

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Product Name

tert-Amyl methyl ether, 97%

InChI key

HVZJRWJGKQPSFL-UHFFFAOYSA-N

InChI

1S/C6H14O/c1-5-6(2,3)7-4/h5H2,1-4H3

SMILES string

CCC(C)(C)OC

assay

97%

form

liquid

refractive index

n20/D 1.389 (lit.)
n20/D 1.3896

bp

85-86 °C (lit.)

density

0.76-0.78 g/mL at 25 °C (lit.)

functional group

ether

Quality Level

200

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Application


  • Identification of environmental hazards of gasoline oxygenate tert-amyl methyl ether (TAME).: This study evaluates the environmental risks associated with the use of tert-Amyl methyl ether (TAME) as a gasoline oxygenate. The research highlights potential hazards to environmental and human health, underscoring the need for careful assessment and regulation of TAME use in fuels. (Huttunen et al., 1997).

General description

tert-Amyl methyl ether is an fuel ether oxygenate and has been quantitated in water by membrane extraction ion mobility spectrometry. tert-Amyl methyl ether is also referred to as 2-methoxy-2-methyl butane. Kinetics of ion exchange resin (Amberlyst 18) catalyzed tert-amyl methyl ether reactions have been investigated.

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

19.4 °F - closed cup

flash_point_c

-7 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
MKDB0707
MKCZ9536
MKCZ9534
MKCZ9535
MKCZ9527

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Kinetics of heterogeneously catalyzed tert-amyl methyl ether reactions in the liquid phase.
Rihko LK and Krause AOI.
Industrial & Engineering Chemistry Research, 34(4), 1172-1180 (1995)
Sanna Holopainen et al.
Talanta, 106, 448-453 (2013-04-20)
Fuel oxygenates are environmentally detrimental compounds due to their rapid migration to groundwater. Fuel oxygenates have been reported to cause taste and odour problems in drinking water, and they also have long-term health effects. Feasible analytical methods are required to
Sinikka Vainiotalo et al.
Journal of occupational health, 48(5), 347-357 (2006-10-21)
The exposure of gasoline pump repairers and inspectors to gasoline was studied at service stations and repair shops in Finland in April-June 2004. The average air temperature ranged from 7 degrees C to 16 degrees C and wind speed from
Frank Welsch et al.
Journal of applied toxicology : JAT, 23(6), 387-395 (2003-11-25)
This evaluation was part of a much more comprehensive testing program to characterize the mammalian toxicity potential of the gasoline oxygenator additive tertiary amyl methyl ether (TAME), and was initiated upon a regulatory agency mandate. A developmental toxicity hazard identification
Dorothea M Kujawinski et al.
Journal of environmental monitoring : JEM, 12(1), 347-354 (2010-01-19)
In order to monitor the behaviour of contaminants in the aqueous environment effective enrichment techniques often have to be employed due to their low concentrations. In this work a robust and sensitive purge and trap-gas chromatography-isotope ratio mass spectrometry method
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