281573
(S)-(−)-1-Amino-2-(methoxymethyl)pyrrolidine
95%
Synonym(s):
SAMP
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About This Item
Empirical Formula (Hill Notation):
C6H14N2O
CAS Number:
Molecular Weight:
130.19
Beilstein:
1523794
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
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Assay
95%
form
liquid
optical activity
[α]20/D −79°, neat
optical purity
ee: 97% (GLC)
refractive index
n20/D 1.465 (lit.)
bp
42 °C/1.8 mmHg (lit.)
density
0.97 g/mL at 25 °C (lit.)
functional group
ether
SMILES string
COC[C@@H]1CCCN1N
InChI
1S/C6H14N2O/c1-9-5-6-3-2-4-8(6)7/h6H,2-5,7H2,1H3/t6-/m0/s1
InChI key
BWSIKGOGLDNQBZ-LURJTMIESA-N
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Application
(S)-(-)-1-Amino-2-(methoxymethyl)pyrrolidine may be used as a chiral auxiliary in the asymmetric synthesis of (S)-2-ethylhexanoic acid and (S)-2-n-propyl-4-pentenoic acid. It can undergo 1,4-addition to (E)-alkenyl-cyclohexyl sulfonates in the presence of zinc bromide to form β-hydrazino-cyclohexyl sulfonates.
Undergoes condensation reactions with carbonyl compounds to produce hydrazones which are useful synthons in highly enantioselective syntheses.
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
161.6 °F - closed cup
Flash Point(C)
72 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Yuanxia Qin et al.
Journal of agricultural and food chemistry, 67(11), 3168-3178 (2019-02-26)
In this study we report a secretory protein that was purified from Serratia marcescens strain S3 isolated from soil from the tobacco rhizosphere. Subsequent mass spectrometry and annotation characterized the protein as secretory alkaline metalloprotease (SAMP). SAMP plays a crucial
Synlett, 897-897 (1992)
Synthesis, 725-725 (1993)
Asymmetric Synthesis of ?-Amino-cyclohexyl Sulfonates via azaMichael Addition
Enders D and Wallert S.
Synlett, 2002(02), 0304-0306 (2002)
Luca Di Martino et al.
Cellular and molecular gastroenterology and hepatology, 8(3), 427-446 (2019-06-11)
Crohn's disease (CD) is a debilitating inflammatory disorder that affects more than 1.6 million people in North America alone. Members of the tumor necrosis factor superfamily are key regulators of intestinal inflammation; specifically, tumor necrosis factor-like weak inducer of apoptosis
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