All Photos(2)
Linear Formula:
CH3OCH2COCH2COOCH3
CAS Number:
Molecular Weight:
146.14
Beilstein:
1761215
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Assay
97%
form
liquid
refractive index
n20/D 1.431 (lit.)
bp
89 °C/8.5 mmHg (lit.)
density
1.129 g/mL at 25 °C (lit.)
SMILES string
COCC(=O)CC(=O)OC
InChI
1S/C6H10O4/c1-9-4-5(7)3-6(8)10-2/h3-4H2,1-2H3
InChI key
QGBPKJFJAVDUNC-UHFFFAOYSA-N
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Application
Methyl 4-methoxyacetoacetate has been used in generation of a small focused library of diversely functionalized dihydropyrimidine derivatives via one-pot three-component Biginelli cyclocondensation of β-ketoesters, aldehydes and (thio)ureas.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
188.6 °F
Flash Point(C)
87 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Doris Dallinger et al.
Nature protocols, 2(7), 1713-1721 (2007-07-21)
Here we report the generation of a small focused library of 12 diversely functionalized dihydropyrimidine (DHPM) derivatives via one-pot three-component Biginelli cyclocondensation of beta-ketoesters, aldehydes and (thio)ureas. By applying controlled microwave heating under sealed vessel conditions using a fully automated
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