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281042

Sigma-Aldrich

Tetradecafluorohexane

99%

Synonym(s):

Perfluorohexane

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About This Item

Linear Formula:
CF3(CF2)4CF3
CAS Number:
355-42-0
Molecular Weight:
338.04
Beilstein:
1802113
EC Number:
206-585-0
MDL number:
MFCD00000437
UNSPSC Code:
12352100
PubChem Substance ID:
24856965
NACRES:
NA.22

Quality Level

100

Assay

99%

form

liquid

refractive index

n20/D 1.252 (lit.)

bp

58-60 °C (lit.)

mp

-74 °C (lit.)

density

1.669 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/C6F14/c7-1(8,3(11,12)5(15,16)17)2(9,10)4(13,14)6(18,19)20

InChI key

ZJIJAJXFLBMLCK-UHFFFAOYSA-N

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General description

Tetradecafluorohexane in the gas phase reacts spontaneously with lithium amalgam, to give a solid and intimate mixture of lithium fluoride and elemental polymeric carbon with a small amount of superstoichiometric lithium.

Application

Tetradecafluorohexane has been used:
  • as a fluorocarbon organic solvent in the preparation of temperature-induced phase-separation solution
  • to investigate boiling heat transfer mechanisms
  • as a photosensitizer in fluorous biphasic singlet oxygenation
  • as a novel reaction medium for photooxidation reactions

accessory

Product No.
Description
Pricing

Hazard Statements

H412

Precautionary Statements

P273 - P501

Hazard Classifications

Aquatic Chronic 3

WGK

WGK 2

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

监管及禁止进口产品

Certificates of Analysis (COA)

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Synthetic Communications, 26, 1861-1861 (1996)
Koichi Kitaguchi et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 30(6), 687-690 (2014-06-13)
A fluorocarbon and hydrocarbon organic solvent mixture is known as a temperature-induced phase-separation solution. When a mixed solution of tetradecafluorohexane as a fluorocarbon organic solvent and hexane as a hydrocarbon organic solvent (e.g., 71:29 volume ratio) was delivered in a
Journal of the American Chemical Society, 118, 5312-5312 (1996)
Michael P Grubb et al.
Nature chemistry, 8(11), 1042-1046 (2016-10-22)
Spectroscopically observing the translational and rotational motion of solute molecules in liquid solutions is typically impeded by their interactions with the solvent, which conceal spectral detail through linewidth broadening. Here we show that unique insights into solute dynamics can be
Journal of Heat Transfer, 118, 429-429 (1996)
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