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Sigma-Aldrich

Tributylhexadecylphosphonium bromide

97%

Synonym(s):

Hexadecyltributylphosphonium bromide, TBHDPB

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About This Item

Linear Formula:
CH3(CH2)15P+[(CH2)3CH3]3Br-
CAS Number:
14937-45-2
Molecular Weight:
507.65
Beilstein:
4167404
EC Number:
239-014-9
MDL number:
MFCD00011775
UNSPSC Code:
12352001
PubChem Substance ID:
24856693
NACRES:
NA.22

Quality Level

100

Assay

97%

form

solid

mp

56-58 °C (lit.)

SMILES string

[Br-].CCCCCCCCCCCCCCCC[P+](CCCC)(CCCC)CCCC

InChI

1S/C28H60P.BrH/c1-5-9-13-14-15-16-17-18-19-20-21-22-23-24-28-29(25-10-6-2,26-11-7-3)27-12-8-4;/h5-28H2,1-4H3;1H/q+1;/p-1

InChI key

RYVBINGWVJJDPU-UHFFFAOYSA-M

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General description

Tributylhexadecylphosphonium bromide (Tri-n-butylhexadecylphosphonium Bromid) has a long hydrocarbon chain attached to the phosphorus atom. It is commonly used as a phase-transfer catalyst in various chemical reactions. In addition, it is also used as a cationic surfactant.

Application

Tributylhexadecylphosphonium bromide can be used as a phase transfer catalyst in the alkaline hydrolysis of PET (polyethylene terephthalate).

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Qiang Li et al.
Carbohydrate polymers, 256, 117592-117592 (2021-01-24)
Historical monuments are increasingly being threatened by unexpected microbial colonizers, leading to their subsequent deterioration. Here, two tetraalkylphosphonium polyoxometalate ionic liquids (Q14-IL and Q16-IL) were successfully synthesized, which showed excellent antibacterial activity against four bacteria colonising wall paintings. Notably, Q14-IL
Tri-n-butylhexadecylphosphonium Bromide
Makosza M, et al
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2001)
Quantification of poly (ethylene terephthalate) micro-and nanoparticle contaminants in marine sediments and other environmental matrices
Castelvetro V, et al.
Journal of Hazardous Materials, 385, 121517-121517 (2020)
Katarzyna Wasilewska et al.
Polymers, 11(3) (2019-04-10)
The taste of drugs is an important factor affecting pharmacotherapy effectiveness, and obtaining formulations with acceptable organoleptic properties is still an ongoing issue in pharmaceutical technology. One of the innovative methods of taste masking is preparation of microparticles by the
A shrinking core model for the alkaline hydrolysis of PET assisted by tributylhexadecylphosphonium bromide
L'opez-Fonseca R, et al.
Chemical Engineering Journal, 146(2), 287-294 (2009)
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