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Merck
CN

275131

Bis(1,5-cyclooctadiene)diiridium(I) dichloride

97%

Synonym(s):

[Ir(1,5-cod)Cl]2, 1,5-Cyclooctadiene-iridium(I) chloride dimer, Chloro(1,5-cyclooctadiene)iridium(I) dimer, Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium, Iridium(I) chloride 1,5-cyclooctadiene complex dimer, [Ir(1,5-cod)Cl]2, [Ir(cod)Cl]2

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About This Item

Empirical Formula (Hill Notation):
C16H24Cl2Ir2
CAS Number:
12112-67-3
Molecular Weight:
671.70
UNSPSC Code:
12352300
PubChem Substance ID:
24856629
EC Number:
235-170-7
MDL number:
MFCD00012414

Key Documents

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InChI key

ZFOUDQNHNLDNLD-MIXQCLKLSA-L

InChI

1S/2C8H12.2ClH.2Ir/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;

SMILES string

Cl[Ir].Cl[Ir].C1CC=CCCC=C1.C2CC=CCCC=C2

assay

97%

reaction suitability

reagent type: catalyst
core: iridium

mp

205 °C (dec.) (lit.)

Application

Metal precursor for asymmetric allylic substitutions.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBN7776V
08729AHV
06506KJ
04324DJ
05731JH

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P A Marks et al.
Journal of the National Cancer Institute, 92(15), 1210-1216 (2000-08-03)
Histone deacetylase (HDAC) inhibitors have been shown to be potent inducers of growth arrest, differentiation, and/or apoptotic cell death of transformed cells in vitro and in vivo. One class of HDAC inhibitors, hydroxamic acid-based hybrid polar compounds (HPCs), induce differentiation

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