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274712

N,N′-Bis(salicylidene)ethylenediaminocobalt(II)

Name: <I>N</I>,<I>N</I>′-Bis(salicylidene)ethylenediaminocobalt(II)
Brand: ALDRICH

99%

Synonym(s):

Co(salen), N,N′-Disalicylidene-ethylenediamine cobalt(II) salt, Co(SALEN)₂, Ethylenebis(salicylimine) cobalt(II) salt, Salcomine

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About This Item

Linear Formula:

[-CH₂N=CHC₆H₄-2-(O-)]₂Co

CAS Number:

14167-18-1

Molecular Weight:

325.23

EC Number:

238-012-5

MDL number:

MFCD00000009

UNSPSC Code:

12161600

PubChem Substance ID:

24856599

NACRES:

NA.22

Assay

99%

reaction suitability

core: cobalt
reagent type: catalyst

SMILES string

C1C\N=C\c2ccccc2O[Co]Oc3ccccc3\C=N\1

InChI

1S/C16H16N2O2.Co/c19-15-7-3-1-5-13(15)11-17-9-10-18-12-14-6-2-4-8-16(14)20;/h1-8,11-12,19-20H,9-10H2;/q;+2/p-2/b17-11+,18-12+;

InChI key

NPAQSKHBTMUERN-OYJDLGDISA-L

Related Categories

Transition Metal Catalysts

Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Inhibition of human cytomegalovirus proteinase by salcomine derivatives.

S Watanabe et al.

Antiviral chemistry & chemotherapy, 9(3), 269-274 (1999-01-06)

Salcomine, N,N'-bis(salicylidene)ethylene diamino-cobalt (II), and its derivatives were evaluated for their ability to inhibit selectively human cytomegalovirus (HCMV) proteinase activity. The 50% inhibitory concentration (IC50) of salcomine was 1.4 microM for HCMV proteinase, but > 200 microM for three other

Preliminary experimental results of gas recycling subsystems except carbon dioxide concentration.

K Otsuji et al.

Advances in space research : the official journal of the Committee on Space Research (COSPAR), 7(4), 69-72 (1987-01-01)

Oxygen concentration and separation is an essential factor for air recycling in a CELSS. Furthermore, if the value of the plant assimilatory quotient is not coincident with that of the animal respiratory quotient, the recovery of O2 from the concentrated

The synthesis of the pyranonaphthoquinones dehydroherbarin and anhydrofusarubin using Wacker oxidation methodology as a key step and other unexpected oxidation reactions with ceric ammonium nitrate and salcomine.

Adushan Pillay et al.

Organic & biomolecular chemistry, 10(38), 7809-7819 (2012-08-24)

The synthesis of two closely related pyranonaphthoquinones, dehydroherbarin and anhydrofusarubin, is described. The construction of the naphthalene nuclei was achieved using the Stobbe condensation reaction using 2,4-dimethoxybenzaldehyde and 2,4,5-trimethoxybenzaldehyde as their respective starting materials. Two key steps en route include

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