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Merck
CN

268038

Methyl oleate

technical grade, 70%

Synonym(s):

Methyl cis-9-octadecenoate, Oleic acid methyl ester

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About This Item

Linear Formula:
CH3(CH2)7CH=CH(CH2)7CO2CH3
CAS Number:
112-62-9
Molecular Weight:
296.49
Beilstein:
1727037
EC Number:
203-992-5
MDL number:
MFCD00009578
UNSPSC Code:
12352100
PubChem Substance ID:
24856258
NACRES:
NA.22

Key Documents

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grade

technical grade

Quality Level

100

vapor pressure

10 mmHg ( 205 °C)

Assay

70%

form

liquid

refractive index

n20/D 1.452 (lit.)

bp

218 °C/20 mmHg (lit.)

density

0.874 g/mL at 20 °C (lit.)

functional group

ester

SMILES string

CCCCCCCC\C=C/CCCCCCCC(=O)OC

InChI

1S/C19H36O2/c1-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19(20)21-2/h10-11H,3-9,12-18H2,1-2H3/b11-10-

InChI key

QYDYPVFESGNLHU-KHPPLWFESA-N

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General description

The methyl oleate monolayers at the air-water interface undergoes ozonolysis that results in rapid loss of material through cleavage of the C[double bond]C bond and evaporation/dissolution of reaction products.

Application

Methyl oleate was used to study the catalytic potential of molybdenum oxide/bipyridinedicarboxylate hybrid material.

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113.0 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
SDBB5743
MKBF2291V
STBK9281
STBK1264
STBJ6278

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Tatiana R Amarante et al.
Inorganic chemistry, 52(8), 4618-4628 (2013-03-28)
The reaction of MoO3, 2,2'-bipyridine-5,5-dicarboxylic acid (H2bpdc), water, and dimethylformamide in the mole ratio 1:1:1730:130 at 150 °C for 3 days in a rotating Teflon-lined digestion bomb leads to the isolation of the molybdenum oxide/bipyridinedicarboxylate hybrid material (DMA)[MoO3(Hbpdc)]·nH2O (1) (DMA
Hailey M Summers et al.
Bioresource technology, 196, 431-440 (2015-08-16)
The economic feasibility and environmental impact is investigated for the conversion of agricultural waste, delactosed whey permeate, through yeast fermentation to a renewable diesel via hydrothermal liquefaction. Process feasibility was demonstrated at laboratory-scale with data leveraged to validate systems models
Christian Pfrang et al.
Physical chemistry chemical physics : PCCP, 16(26), 13220-13228 (2014-05-30)
Ozonolysis of methyl oleate monolayers at the air-water interface results in surprisingly rapid loss of material through cleavage of the C=C bond and evaporation/dissolution of reaction products. We determine using neutron reflectometry a rate coefficient of (5.7 ± 0.9) ×
Cyril Thurier et al.
ChemSusChem, 1(1-2), 118-122 (2008-07-09)
Unsaturated vegetable oils are an attractive renewable feedstock, and the selective cleavage of unsaturated fatty esters is an important transformation in this respect. The efficient and selective cross-metathesis of methyl oleate with ethylene was achieved under mild conditions with ruthenium-alkylidene
Renee M Thomas et al.
Journal of the American Chemical Society, 133(19), 7490-7496 (2011-04-23)
N-Aryl,N-alkyl N-heterocyclic carbene (NHC) ruthenium metathesis catalysts are highly selective toward the ethenolysis of methyl oleate, giving selectivity as high as 95% for the kinetic ethenolysis products over the thermodynamic self-metathesis products. The examples described herein represent some of the
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