266841
Iridium
wire, diam. 0.15 mm, 99.9% trace metals basis
Synonym(s):
Iridium black
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About This Item
Empirical Formula (Hill Notation):
Ir
CAS Number:
Molecular Weight:
192.22
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352300
MDL number:
InChI
1S/Ir
SMILES string
[Ir]
InChI key
GKOZUEZYRPOHIO-UHFFFAOYSA-N
assay
99.9% trace metals basis
form
wire
resistivity
4.71 μΩ-cm
diam.
0.15 mm
bp
4130 °C (lit.)
mp
2450 °C (lit.)
density
22.65 g/cm3 (lit.)
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Preparation Note
40mg=10cm, 400mg=100cm
Storage Class
13 - Non Combustible Solids
wgk
nwg
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Daniel Shiu-Hin Chan et al.
PloS one, 8(3), e60114-e60114 (2013-03-28)
We report herein a novel luminescent iridium(III) complex with two hydrophobic carbon chains as a non-reaction based chemosensor for the detection of Hg(2+) ions in aqueous solution (<0.002% of organic solvent attributed to the probe solution). Upon the addition of
Carl W Liskey et al.
Journal of the American Chemical Society, 135(9), 3375-3378 (2013-02-21)
The borylation of cyclopropanes catalyzed by the combination of (η(6)-mes)IrBpin3 or [Ir(COD)OMe]2 and a phenanthroline derivative is reported. The borylation occurs selectively at the methylene C-H bonds of the cyclopropane ring over methine or methyl C-H bonds. High diasteroselectivities were
Enantioselective iridium-catalyzed hydrogenation of 1- and 3-substituted isoquinolinium salts.
Zhi-Shi Ye et al.
Angewandte Chemie (International ed. in English), 52(13), 3685-3689 (2013-02-21)
Le Guo et al.
Organic letters, 15(5), 1144-1147 (2013-02-16)
The first α-alkylation of unactivated amides with primary alcohols is described. An effective and robust iridium pincer complex has been developed for selective α-alkylation of tertiary and secondary acetamides involving a "borrowing hydrogen" methodology. The method is compatible with alcohols
José Luis Núñez-Rico et al.
Organic letters, 15(8), 2066-2069 (2013-04-12)
Iridium(I) complexes of enantiomerically pure phosphine-phosphite ligands ([Ir(Cl)(cod)(P-OP)]) efficiently catalyze the enantioselective hydrogenation of diverse C═N-containing heterocyclic compounds (benzoxazines, benzoxazinones, benzothiazinones, and quinoxalinones; 25 examples, up to 99% ee). A substrate-to-catalyst ratio as high as 2000:1 was reached.
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