263613
Diethyl chloromethylphosphonate
97%
Synonym(s):
Chloromethylphosphonic acid diethyl ester, NSC 67753
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About This Item
InChI key
MZBIWKMCTWJLPT-UHFFFAOYSA-N
InChI
1S/C5H12ClO3P/c1-3-8-10(7,5-6)9-4-2/h3-5H2,1-2H3
SMILES string
CCOP(=O)(CCl)OCC
assay
97%
reaction suitability
reaction type: C-C Bond Formation
refractive index
n20/D 1.437 (lit.)
bp
109-110 °C/10 mmHg (lit.)
density
1.2 g/mL at 25 °C (lit.)
Application
- Subsequent alkylation after nucleophilic substitution
- One-pot alkylation-boration of α-haloalkylphosphonates
- Synthesis of cyclpentane and pyrrolidine derivatives via regioselective insertion reactions
- Phosphorylation leading to P-containing cyclopropanes
- Wadsworth-Emmons reactions
- Ring expansion of zircnacycles via carbenoid insertion
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
186.8 °F - closed cup
flash_point_c
86 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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