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262056

Sigma-Aldrich

Dibromoborane dimethyl sulfide complex solution

1.0 M in methylene chloride

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Synonym(s):
Dibromo(dimethyl sulfide)(hydro)boron solution, Dibromo(dimethyl sulfide)borane solution, Dibromoborane compound with dimethylsulfane solution, Dibromoborane dimethyl sulfide solution
Linear Formula:
(CH3)2S · BHBr2
CAS Number:
Molecular Weight:
233.76
Beilstein:
4449985
MDL number:
UNSPSC Code:
12352112
PubChem Substance ID:
NACRES:
NA.22

form

liquid

Quality Level

reaction suitability

reagent type: reductant

concentration

1.0 M in methylene chloride

density

1.415 g/mL at 25 °C

SMILES string

CSC.BrBBr

InChI

1S/C2H6S.BBr2H/c1-3-2;2-1-3/h1-2H3;1H

InChI key

PGSRDLGPKTVELT-UHFFFAOYSA-N

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Application

Reactant for:
  • Reductive elimination C-C bond forming reactions
  • Lithiation-borylation reaction with Hoppe′s lithiated carbamates
  • Preparation of boron analogues of uracil
  • Boronation reactions for formation of cyclic boronium salts
  • Hydroboration reactions
  • Ring opening of terminal epoxides

Signal Word

Danger

Hazard Statements

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3 - Water-react 2

Target Organs

Central nervous system

Supplementary Hazards

WGK

WGK 3

Flash Point(F)

80.6 °F

Flash Point(C)

27 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品

Certificates of Analysis (COA)

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