258709
4-Methoxythioanisole
97%
Synonym(s):
1-Methoxy-4-(methylthio)benzene
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About This Item
Linear Formula:
CH3OC6H4SCH3
CAS Number:
Molecular Weight:
154.23
UNSPSC Code:
12352100
PubChem Substance ID:
MDL number:
Assay:
97%
Form:
solid
InChI
1S/C8H10OS/c1-9-7-3-5-8(10-2)6-4-7/h3-6H,1-2H3
SMILES string
COc1ccc(SC)cc1
InChI key
DQNSKXYRRRCKGH-UHFFFAOYSA-N
assay
97%
form
solid
refractive index
n20/D 1.5795 (lit.)
bp
99 °C/4 mmHg (lit.)
mp
22-23 °C (lit.)
density
1.11 g/mL at 25 °C (lit.)
Application
4-Methoxythioanisole has been used in preparation of 1-methoxy-4-(methylsulfinyl)benzene.
Other Notes
Contains 4-chloroanisole
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
226.4 °F - closed cup
flash_point_c
108 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Iron-catalyzed selective oxidation of sulfides to sulfoxides with the polyethylene glycol/O2 system.
Li B, et al.
Green Chemistry, 14(1), 130-135 (2012)
U Pérez et al.
Biochemistry, 29(11), 2757-2763 (1990-03-20)
Transient-state reactions of horseradish peroxidase compounds I and II with 1-methoxy-4-(methylthio)benzene (a para-substituted thioanisole) were studied over the pH range from 3.4 to 10.5. The pH-jump technique was applied to the compound II reactions at pH values below 8.6. The
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