Skip to Content
Merck
CN
All Photos(1)

Documents

Safety Information

256021

Sigma-Aldrich

(Trimethylsilyl)methylmagnesium chloride solution

1.0 M in diethyl ether

Synonym(s):

(Trimethylsilyl)methyl magnesium chloride, Chloro(trimethylsilylmethyl)magnesium

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
(CH3)3SiCH2MgCl
CAS Number:
Molecular Weight:
146.97
Beilstein:
3587255
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

Quality Level

reaction suitability

reaction type: Grignard Reaction

concentration

1.0 M in diethyl ether

density

0.777 g/mL at 25 °C

SMILES string

C[Si](C)(C)C[Mg]Cl

InChI

1S/C4H11Si.ClH.Mg/c1-5(2,3)4;;/h1H2,2-4H3;1H;/q;;+1/p-1

InChI key

NAQATMJWCJCHOZ-UHFFFAOYSA-M

Looking for similar products? Visit Product Comparison Guide

Related Categories

Application

Reagent used in a variety of nickel catalyzed reactions including alkenation of dithioacetals, cross-coupling with aryl triflates and carbamates, and cross-coupling with vinyl selenides.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

-40.0 °F - closed cup

Flash Point(C)

-40 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品
易制毒化学品(2类)

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Tetrahedron Letters, 35, 6729-6729 (1994)
Accounts of Chemical Research, 24, 257-257 (1991)
The Journal of Organic Chemistry, 57, 4066-4066 (1992)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service