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Merck
CN

254304

Lithium tetraborate

≥99.995% trace metals basis

Synonym(s):

Dilithium tetraborate

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About This Item

Linear Formula:
Li2B4O7
CAS Number:
Molecular Weight:
169.12
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
234-514-3
MDL number:
Assay:
≥99.995% trace metals basis
Form:
powder
Solubility:
H2O: slightly soluble(lit.)
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Product Name

Lithium tetraborate, ≥99.995% trace metals basis

InChI key

PSHMSSXLYVAENJ-UHFFFAOYSA-N

InChI

1S/B4O7.2Li/c5-1-9-3(7)11-4(8)10-2-6;;/q-2;2*+1

SMILES string

[Li+].[Li+].[O-]B(OB=O)OB([O-])OB=O

assay

≥99.995% trace metals basis

form

powder

reaction suitability

core: lithium

impurities

≤50.0 ppm Trace Metal Analysis

mp

760-880 °C (lit.)

solubility

H2O: slightly soluble(lit.)

density

≥0.25 g/mL at 25 °C (lit.)

Quality Level

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Application

Lithium tetraborate may be used as an analytical reagent for the analysis of major and trace elements in coal fly ashes and environmental materials using inductively coupled plasma atomic emission spectrometry (ICP-AES). It may also be used as an alkali fusion reagent for the determination of silicon in zirconium oxide powder using ICP-AES.

General description

Lithium tetraborate in combination with oxalic acids and lithium carbonate in the ratio (1:1:1) may be used as an effective fusing agent for siliceous samples. It is widely employed in lithium tetraborate fusion procedure, suited for a variety of soils and rocks. Lithium tetraborate also finds applications in radiation detectors and dosimeters.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 2

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Contamination-free decomposition of zirconium oxide for the determination of ultra-trace silicon by inductively coupled plasma-atomic emission spectrometry
Watanabe M, et al.
Analytica Chimica Acta, 416(1), 117-119 (2000)
Analysis of siliceous materials and coal by atomic absorption spectrophotometry with fusion for sample decomposition
Lau W-O, et al.
Talanta, 51(5), 1009-1018 (2000)
Sparks LD, et al.
Methods of Soil Analysis, Part 3: Chemical Methods, 14 (2020)
Analysis of coal fly ash and environmental materials by inductively coupled plasma atomic emission spectrometry: comparison of different decomposition procedures
Bettinelli M, et al.
Journal of Analytical Atomic Spectrometry, 2(5), 485-489 (1987)
Development of a qualitative, multiplex real-time PCR kit for screening of genetically modified organisms (GMOs)
Dorries H-H, et al.
Analytical and Bioanalytical Chemistry, 396(6), 2043-2054 (2010)

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