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Merck
CN

249998

Titanium(III) chloride solution

~10 wt. % in 20-30 wt. % hydrochloric acid

Synonym(s):

Titanium trichloride

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About This Item

Linear Formula:
TiCl3
CAS Number:
7705-07-9
Molecular Weight:
154.23
UNSPSC Code:
12352301
PubChem Substance ID:
57648103
MDL number:
MFCD00011266

Key Documents

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InChI

1S/3ClH.Ti/h3*1H;/q;;;+3/p-3

SMILES string

Cl[Ti](Cl)Cl

InChI key

YONPGGFAJWQGJC-UHFFFAOYSA-K

reaction suitability

reagent type: catalyst
core: titanium

concentration

~10 wt. % in 20-30 wt. % hydrochloric acid

density

1.192 g/mL at 25 °C

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Application

Catalyst for:
Hydrogen desorption properties
Nitrogen-nitrogen reductive bond cleavage

Reagent for:
Photocatalyst synthesis
Preparation of nanostructures titania/cetyltrimethyammonium bromide nanoskeleton

Other Notes

Exact concentration stated on label

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
SHBC4028V
57396APV
57396AP
05796HM
15096MK

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S. Isobe, et al.,
Applied Physics Letters, 99 (2011)
Shuxi Dai et al.
Nanoscale research letters, 5(11), 1829-1835 (2010-12-03)
Highly crystalline TiO(2) nanostructures were prepared through a facile inorganic acid-assisted hydrothermal treatment of hexagonal-structured assemblies of nanocrystalline titiania templated by cetyltrimethylammonium bromide (Hex-ncTiO(2)/CTAB Nanoskeleton) as starting materials. All samples were characterized by X-ray diffraction (XRD) and transmission electron microscopy
D. Meroni, et al
Catalysis Today, 161, 169-174 (2011)
Jun-ichi Matsuo et al.
Organic letters, 12(14), 3266-3268 (2010-06-24)
N-p-Toluenesulfonyl (Ts) aldimines reacted with 3-ethoxycyclobutanones by catalysis of titanium(IV) chloride to afford 2,3-di- or 2,3,3-trisubstituted N-Ts-2,3-dihydro-4-pyridones. Synthesis of (+/-)-bremazocine was efficiently accomplished by using this method.
Gema Ruano et al.
The Journal of organic chemistry, 68(5), 2024-2027 (2003-03-01)
Enantiomerically pure N-substituted epoxyalkene-2-azetidinones reacted with titanocene monochloride to give stereospecifically polyfunctionalized bicyclic beta-lactams. Four isomeric epoxyaldehydes 2 reacted with TiCp2Cl to give exclusively the respective carbacephams 7 while under the same reaction conditions the epoxyesters 1, which are more
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