249920
Silicon tetrachloride solution
1.0 M in methylene chloride
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About This Item
Linear Formula:
SiCl4
CAS Number:
Molecular Weight:
169.90
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/Cl4Si/c1-5(2,3)4
SMILES string
Cl[Si](Cl)(Cl)Cl
InChI key
FDNAPBUWERUEDA-UHFFFAOYSA-N
vapor density
5.86 (vs air)
form
liquid
concentration
1.0 M in methylene chloride
density
1.34 g/mL at 25 °C
Quality Level
Related Categories
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Carc. 2 - Eye Dam. 1 - Skin Corr. 1A - STOT SE 3
target_organs
Central nervous system
supp_hazards
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
危险化学品
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D Khushalani et al.
Journal of nanoscience and nanotechnology, 1(2), 129-132 (2003-08-14)
Mesostructured silica-nanoparticle monolithic composites have been synthesized by dispersing prefabricated nanoparticles of gold or zeolite (silicalite) in ethanolic reaction mixtures containing SiCl4 and a Pluronic triblock copolymer template. Whereas silicalite nanoparticles were used directly, surface functionalization of the gold nanoparticles
Pulmonary interstitial emphysema: CT findings.
A C Kemper et al.
AJR. American journal of roentgenology, 172(6), 1642-1642 (1999-06-01)
K M Sivanandaiah et al.
International journal of peptide and protein research, 45(4), 377-379 (1995-04-01)
Deprotection of the tert-butoxycarbonyl group during solid-phase synthesis of peptides can be conveniently and efficiently carried out using a neutral reagent, silicon tetrachloride/sodium iodide (iodotrichlorosilane). This simple and rapid method has been advantageously employed during the solid-phase synthesis of the
Claudio Curti et al.
Organic letters, 13(17), 4738-4741 (2011-08-13)
Virtually perfect transmittal of the enolate reactivity up to five conjugated double bonds from the origin allows a series of furan-based silyloxypolyenes to add to aldehyde carbonyls at the most distant point of the molecule. Denmark's axially chiral bisphosphoramide/SiCl(4) combination
Sang Ho Lee et al.
Journal of the American Chemical Society, 127(25), 9071-9078 (2005-06-23)
A series of four asymmetrically aryl-substituted 9,9'-spiro-9-silabifluorene (SSF) derivatives, 2,2'-di-tert-butyl-7,7'-diphenyl-9,9'-spiro-9-silabifluorene (PhSSF), 2,2'-di-tert-butyl-7,7'-dipyridin-2-yl-9,9'-spiro-9-silabifluorene (PySSF), 2,2'-di-tert-butyl-7,7'-dibiphenyl-4-yl-9,9'-spiro-9-silabifluorene (BPhSSF), and 2,2'-di-tert-butyl-7,7'-bis(2',2' '-bipyridin-6-yl)-9,9'-spiro-9-silabifluorene (BPySSF) are prepared through the cyclization of the corresponding 2,2'-dilithiobiphenyls with silicon tetrachloride. These novel spiro-linked silacyclopentadienes (siloles) form transparent and stable
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