All Photos(1)
Synonym(s):
α-Bromopropanyl bromide, α-Bromopropionyl bromide, (±)-2-Bromopropanoyl bromide, 2-Bromopropanoyl bromide
Linear Formula:
CH3CHBrCOBr
CAS Number:
Molecular Weight:
215.87
Beilstein:
1071331
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
vapor density
7.5 (vs air)
Quality Level
vapor pressure
1.3 mmHg ( 20 °C)
Assay
97%
form
liquid
refractive index
n20/D 1.518 (lit.)
bp
48-50 °C/10 mmHg (lit.)
density
2.061 g/mL at 25 °C (lit.)
SMILES string
CC(Br)C(Br)=O
InChI
1S/C3H4Br2O/c1-2(4)3(5)6/h2H,1H3
InChI key
ILLHORFDXDLILE-UHFFFAOYSA-N
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Related Categories
Application
2-Bromopropionyl bromide has been used in the synthesis of:
- cellulose macroinitiator via direct acylation of cellulose in ionic liquid 1-allyl-3-methylimidazolium chloride
- 3-(2-bromopropionyl)-2-oxazolidone derivatives
- bromoester terminated poly(3-hexylthiophene), used as macroinitiator for atom transfer radical polymerization of acrylates.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Skin Corr. 1B
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
危险化学品
Certificates of Analysis (COA)
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A highly stereoselective synthesis of a key intermediate of 1?-methylcarbapenems employing the reformatsky reaction of 3-(2-bromopropionyl)-2-oxazolidone derivatives.
Ito Y and Terashima S.
Tetrahedron Letters, 28(52), 6625-6628 (1987)
Xiaofeng Sui et al.
Biomacromolecules, 9(10), 2615-2620 (2008-09-09)
Cellulose-graft-poly(N,N-dimethylamino-2-ethyl methacrylate) (cellulose-g-PDMAEMA) copolymers were prepared by homogeneous atom transfer radical polymerization (ATRP) under mild conditions. Cellulose macroinitiator was successfully synthesized by direct acylation of cellulose with 2-bromopropionyl bromide in a room temperature ionic liquid (RTIL), 1-allyl-3-methylimidazolium chloride. Copolymers were
Regioregular poly (3-alkylthiophene) conducting block copolymers.
Iovu MC, et al.
Polymer, 46(19), 8582-8586 (2005)
Yanfei Hu et al.
International journal of pharmaceutics, 491(1-2), 152-161 (2015-06-23)
Thermo-responsive brush-like amphiphilic poly[2-(2-methoxyethoxy) ethyl methacrylate-co-oligo(ethylene glycol) methacrylate]-b-poly(l-lactide)-b-poly[2-(2-methoxyethoxy) ethyl methacrylate-co-oligo(ethylene glycol) methacrylate] [P(MEO2MA-co-OEGMA)-b-PLLA-b-P(MEO2MA-co-OEGMA)] triblock copolymers were synthesized by atom transfer radical polymerization of MEO2MA and OEGMA co-monomers using a α,ω-Bromopropionyl poly(l-lactide) (Br-PLLA-Br) macroinitiator. The resulting copolymers with MEO2MA/OEGMA molar ratio
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