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247650

Sigma-Aldrich

Hexarhodium(0) hexadecacarbonyl

Rh 57-60 % (approx.)

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Synonym(s):
Rhodium(0) carbonyl
Linear Formula:
Rh6(CO)16
CAS Number:
28407-51-4
Molecular Weight:
1065.59
EC Number:
249-009-3
MDL number:
MFCD00011206
UNSPSC Code:
12161600
PubChem Substance ID:
24854881
NACRES:
NA.22

composition

Rh, 57-60% (approx.)

Quality Level

100

reaction suitability

core: rhodium
reagent type: catalyst

SMILES string

[Rh].[Rh].[Rh].[Rh].[Rh].[Rh].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/16CO.6Rh/c16*1-2;;;;;;

InChI key

SZQABOJVTZVBHE-UHFFFAOYSA-N

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Application

Catalyst for hydrogenation of alkenes, hydroformylations ofalkenes; reducing agent for aldehydes, ketones, and nitro groups; catalyst for carbenoid reactions of diazo compounds
Widely used organometallic catalyst. Applications include the hydroformylation of olefins.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302 + H312 + H332

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Journal of Materials Chemistry, 5, 75-75 (1995)
Ojima, I.; Kato, K.; Okabe, M.; Fuchikami, T.
Journal of the American Chemical Society, 109, 7714-7714 (1987)
Murahashi, S.; Imada, Y.; Hirai, Y.
Bulletin of the Chemical Society of Japan, 62, 2968-2968 (1989)
Journal of the American Ceramic Society. American Ceramic Society, 78, 1179-1179 (1995)
Crotti, C.; Cenini, S.; Rindone, B. et al.
Journal of the Chemical Society. Chemical Communications, 784-784 (1986)

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