Skip to Content
Merck
CN
All Photos(1)

Documents

Safety Information

247219

Sigma-Aldrich

6-Bromo-1-hexene

95%

Sign Into View Organizational & Contract Pricing
All Photos(1)
Synonym(s):
1-Bromo-5-hexene, 5-Hexen-1-yl bromide, 5-Hexenyl bromide, 6-Bromohexene
Linear Formula:
Br(CH2)4CH=CH2
CAS Number:
2695-47-8
Molecular Weight:
163.06
Beilstein:
506203
MDL number:
MFCD00000269
UNSPSC Code:
12352100
PubChem Substance ID:
24854859
NACRES:
NA.22

Quality Level

200

Assay

95%

form

liquid

impurities

<3% DMF

refractive index

n20/D 1.465 (lit.)

bp

47-51 °C/16 mmHg (lit.)

density

1.22 g/mL at 25 °C (lit.)

SMILES string

BrCCCCC=C

InChI

1S/C6H11Br/c1-2-3-4-5-6-7/h2H,1,3-6H2

InChI key

RIMXEJYJXDBLIE-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

Reaction of 6-bromo-1-hexene with Mg to form Grignard compounds has been investigated. The thermal chemistry of 6-bromo-1-hexene on Ni (100) surface has been studied under ultrahigh vacuum conditions by X-ray photoelectron spectroscopy and temperature-programmed desorption.

Application

6-Bromo-1-hexene was used in the preparation of epoxide, 6-bromo-1,2-epoxyhexane. It was also used in a simple, direct preparation of 4-alkenylbenzonitriles via anionic reduced forms of terephthalonitrile in liquid ammonia.

Signal Word

Danger

Hazard Statements

H226,H315,H319,H335,H360D

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

The formation of grignard compounds-III: The influence of the solvent.
Bodewitz HWHJ, et al.
Tetrahedron, 31(8), 1053-1063 (1975)
Synlett, 1616-1616 (2007)
Cyclization of 6-bromo-1, 2-epoxyhexane promoted by metal-halogen exchange: unexpected regioselectivity.
Babler JH and Bauta WE.
Tetrahedron Letters, 25(39), 4323-4324 (1984)
Thermal chemistry of 1, 6-diiodohexane on Ni (100) single-crystal surfaces: Mimicking cyclization reactions.
Tjandra S and Zaera F.
The Journal of Physical Chemistry A, 103(!4), 2312-2320 (1999)
Hiroshi Toda et al.
Applied and environmental microbiology, 81(6), 1919-1925 (2015-01-04)
We describe the development of biocatalysis for producing optically pure straight-chain (S)-epoxyalkanes using styrene monooxygenase of Rhodococcus sp. strain ST-10 (RhSMO). RhSMO was expressed in the organic solvent-tolerant microorganism Kocuria rhizophila DC2201, and the bioconversion reaction was performed in an
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service