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Sigma-Aldrich

Pentaerythritol tetraacrylate, Pentaerythritol triacrylate, and Trimethylolpropane triacrylate mixture

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Synonym(s):
PTA/TMPTA mixture, Pentaerythritol acrylates mixture
Beilstein:
6598752
EC Number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

contains

300-400 ppm monomethyl ether hydroquinone as inhibitor

Quality Level

refractive index

n20/D 1.483

density

1.18 g/mL at 25 °C

SMILES string

O=C(C=C)OCC(COC(C=C)=O)(COC(C=C)=O)COC(C=C)=O.OCC(COC(C=C)=O)(COC(C=C)=O)COC(C=C)=O.CCC(COC(C=C)=O)(COC(C=C)=O)COC(C=C)=O

General description

Pentaerythritol tetraacrylate, Pentaerythritoltriacrylate, and Trimethylolpropane triacrylate mixture is a combination of three acrylate monomers widely used for cross-linking. The Pentaerythritol-based acrylate mixtureoffers advantages such as improved mechanical strength, flexibility, chemical resistance, and UV-curing properties. It finds applications in industries such as automotive coatings, electronics, packaging, and 3D bioprinting.

Application

Pentaerythritol tetraacrylate, Pentaerythritol triacrylate, and Trimethylolpropane triacrylate mixture can be used:

  • As a cross-linking agent to synthesize biodegradable poly (1,3-trimethylene carbonate) (PTMC) networks with improved creep resistance and thermal stability. PMTC networks find application in the field of soft tissue engineering.
  • As a monomer precursor to prepare light-curing dental composites via photopolymerization.
  • To fabricate polymer-dispersed liquid crystal(PDLC) films with low driving voltage, moderately high contrast ratio, and fast response time. These PDLC films are utilized in optoelectronic devices such as OLEDs, FET, and solar cells.
  • As a monomer mixture to prepare 3D bioprinting resins viaphotopolymerization.

Signal Word

Warning

Hazard Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1

WGK

WGK 2

Flash Point(F)

230.0 °F

Flash Point(C)

110 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Effects of multifunctional acrylates and thiols on the morphology and electro-optical properties of polymer-dispersed liquid crystal films
Mohsin Hassan Saeed, et al.
Emerging Liquid Crystal Technologies V, 48, 1457-1466 (2021)
Marc Hippler et al.
Nature communications, 10(1), 232-232 (2019-01-18)
Stimuli-responsive microstructures are critical to create adaptable systems in soft robotics and biosciences. For such applications, the materials must be compatible with aqueous environments and enable the manufacturing of three-dimensional structures. Poly(N-isopropylacrylamide) (pNIPAM) is a well-established polymer, exhibiting a substantial
Xiaochun Wang et al.
Journal of chromatography. A, 1216(21), 4611-4617 (2009-04-04)
A polar and neutral polymethacrylate-based monolithic column was evaluated as a hydrophilic interaction capillary electrochromatography (HI-CEC) stationary phase with small polar-neutral or charged solutes. The polar sites on the surface of the monolithic solid phase responsible for hydrophilic interactions were
Biodegradable cross-linked poly (1, 3-trimethylene carbonate) networks formed by gamma irradiation under vacuum
Xiliang Liu, et al.
Polymers For Advanced Technologies, 32, 4373-4385 (2021)
Recent trends in advanced photoinitiators for vat photopolymerization 3D printing
Yinyin Bao
Macromolecular Rapid Communications, 43, 2200202-2200202 (2022)

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