246352
Methyl carbamate
98%
Synonym(s):
Urethylane
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About This Item
Linear Formula:
NH2COOCH3
CAS Number:
Molecular Weight:
75.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
209-939-2
MDL number:
Assay:
98%
Form:
crystals
Product Name
Methyl carbamate, 98%
InChI key
GTCAXTIRRLKXRU-UHFFFAOYSA-N
InChI
1S/C2H5NO2/c1-5-2(3)4/h1H3,(H2,3,4)
SMILES string
COC(N)=O
assay
98%
form
crystals
bp
176-177 °C (lit.)
mp
56-58 °C (lit.)
solubility
alcohol: freely soluble(lit.)
water: freely soluble(lit.)
functional group
amine
Quality Level
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Related Categories
Application
Methyl carbamate was used in the synthesis of protected aminocyclopropanes.
signalword
Warning
hcodes
Hazard Classifications
Carc. 2 - Eye Irrit. 2
Storage Class
11 - Combustible Solids
wgk
WGK 3
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
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Shingo Ishikawa et al.
Angewandte Chemie (International ed. in English), 52(38), 10060-10063 (2013-08-06)
Easy as 1,2,3: Reaction of methyl carbamate, triethyl orthoformate, and readily available alkenes provides a highly practical preparation of protected aminocyclopropanes. The reaction proceeds with preferential cis addition to alkenes, and cleavage of the methyl carbamate gives the free aminocyclopropanes
Genotoxicity data supporting the proposed metabolic activation of ethyl carbamate (urethane) to a carcinogen: the problem now posed by methyl carbamate.
J Ashby
Mutation research, 260(4), 307-308 (1991-08-01)
Joshua A Hartsel et al.
Bioorganic & medicinal chemistry letters, 22(14), 4593-4598 (2012-06-29)
To identify potential human-safe insecticides against the malaria mosquito we undertook an investigation of the structure-activity relationship of aryl methylcarbamates inhibitors of acetylcholinesterase (AChE). Compounds bearing a β-branched 2-alkoxy or 2-thioalkyl group were found to possess good selectivity for inhibition
Xiangyun Lin et al.
Journal of separation science, 34(2), 202-209 (2011-01-20)
This paper described a simple, rapid and efficient method for the determination of N-methyl carbamate pesticides in tomato, cucumber, carrot and lettuce samples by dispersive liquid-liquid microextraction coupled with HPLC-diode array detection. Some experimental parameters that influenced the extraction efficiency
D F K Rawn et al.
Food additives and contaminants, 21(6), 555-563 (2004-06-19)
Infants and young children consume fruit juices and drinks at rates exceeding those of older children and adults. Carbamate pesticides are known to be used on a broad spectrum of crops, including orchard and vine crops such as apples and
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