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Merck
CN

245267

Manganese(0) carbonyl

98%

Synonym(s):

Decacarbonyl dimanganese(0), Dimanganese(0) decacarbonyl

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About This Item

Linear Formula:
Mn2(CO)10
CAS Number:
Molecular Weight:
389.98
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
233-445-6
MDL number:
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Product Name

Manganese(0) carbonyl, 98%

InChI key

QFEOTYVTTQCYAZ-UHFFFAOYSA-N

InChI

1S/10CO.2Mn/c10*1-2;;

SMILES string

[Mn].[Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

assay

98%

form

powder or crystals

reaction suitability

core: manganese
reagent type: catalyst

mp

154 °C (lit.)

storage temp.

2-8°C

Quality Level

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Application

Manganese(0) carbonyl can be used:
  • As a precursor to prepare Ni2–xMnxP nanoparticles to fabricate a catalyst for electrochemical oxygen evolution reaction(OER).
  • To fabricate an ultra-sensitive manganese doped MoS2 electrochemical dopamine sensor via modified chemical vapor deposition(CVD) method.
  • As a reducing agent to synthesize Pt-Co electrocatalyst for oxygen reduction reactions in fuel cells. Mn and CO atoms produced during decomposition acts as reducing and surface structure guiding agents respectively.

General description

Manganese(0) carbonyl, also known as Decacarbonyl dimanganese exhibits interesting electrochemicalproperties owing to the presence of carbonyl ligands and the manganese metalcenters. In electrochemistry, this compound can act as a carbonyl source andpotentially participate in redox reactions.

pictograms

Skull and crossbones

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 3 Inhalation

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Doping and decorating 2D materials for biosensing: benefits and drawbacks
Hui Ling Chia, et al.
Advanced Functional Materials , 31, 2102555-2102555 (2021)
Pt-Co Electrocatalysts: Syntheses, Morphologies, and Applications
Hao Chen, et al.
Small, 18, 2204100-2204100 (2022)
Ni2?xMnxP Nanoparticles as Earth-Abundant Precatalysts for Electrochemical Water Oxidation
Fatemeh Aghabozorgi, et al
Chemistry of Materials, 36, 2461-2472 (2024)

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