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Merck
CN

244937

Dichloro(1,5-cyclooctadiene)platinum(II)

Synonym(s):

(1,5-Cyclooctadiene)platinum(II) dichloride, 1,5-Cyclooctadienedichloroplatinum, (1,5-Cyclooctadiene)platinum dichloride, NSC 239486, Pt(COD)Cl2

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About This Item

Empirical Formula (Hill Notation):
C8H12Cl2Pt
CAS Number:
12080-32-9
Molecular Weight:
374.16
NACRES:
NA.22
PubChem Substance ID:
24854718
UNSPSC Code:
12161600
EC Number:
235-144-5
MDL number:
MFCD00012413

Key Documents

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InChI key

VVAOPCKKNIUEEU-PHFPKPIQSA-L

InChI

1S/C8H12.2ClH.Pt/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;

SMILES string

Cl[Pt]Cl.C1CC=CCCC=C1

reaction suitability

core: platinum
reagent type: catalyst

mp

285 °C (dec.) (lit.)

Quality Level

100

Related Categories

Application

Catalyst for:
  • Hydrogenative cyclization of allenynes
  • Stereoselective tandem hydrosilylation-Hiyama coupling reactions
  • Amino alkene cyclohydroamination
  • Hydrative cyclization reactions
  • Direct amination of allylic alcohols under mild conditions

  • Potential anticancer agent

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCX9505
MKCW8566
MKCS9577
MKCR8529
MKCN8383

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Jiaojiao Xu et al.
Soft matter, 15(30), 6116-6126 (2019-07-10)
In this work, according to the characteristic of surface plasmon resonance (SPR) of metallic nanoparticles, we investigated the photo actuation performance of a liquid crystalline elastomer (LCE) nanocomposite with incorporated gold nanoparticles (nano-gold/LCE nanocomposite). The nano-gold/LCE nanocomposites were fabricated by
Deborah Vidick et al.
Beilstein journal of nanotechnology, 6, 1287-1297 (2015-07-23)
Heterometal clusters containing Ru and Au, Co and/or Pt are anchored onto carbon nanotubes and nanofibers functionalized with chelating phosphine groups. The cluster anchoring yield is related to the amount of phosphine groups available on the nanocarbon surface. The ligands

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