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243965

Sigma-Aldrich

Phenylselenyl bromide

98%

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Synonym(s):
Benzeneselenenyl bromide, Benzeneselenyl bromide
Linear Formula:
C6H5SeBr
CAS Number:
34837-55-3
Molecular Weight:
235.97
Beilstein:
2039772
EC Number:
252-238-1
MDL number:
MFCD00000047
UNSPSC Code:
12352100
PubChem Substance ID:
24854643
NACRES:
NA.22

Quality Level

100

Assay

98%

form

solid

bp

107-108 °C/15 mmHg (lit.)

mp

58-62 °C (lit.)

SMILES string

Br[Se]c1ccccc1

InChI

1S/C6H5BrSe/c7-8-6-4-2-1-3-5-6/h1-5H

InChI key

LCEFEIBEOBPPSJ-UHFFFAOYSA-N

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Application

Phenylselenyl bromide was used in the preparation of exo-2-methyl-7-phenylselenyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione and endo-2-methyl-7-phenylselanyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione. It was also used in the synthesis of enones by selenenylation of α-cyano ketones with lithium naphthalenide.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Met. Corr. 1 - STOT RE 2

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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