243906
Borane triphenylphosphine complex
97%
Synonym(s):
Triphenylphosphineborane
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About This Item
Linear Formula:
(C6H5)3P · BH3
CAS Number:
Molecular Weight:
276.12
MDL number:
UNSPSC Code:
12352002
PubChem Substance ID:
NACRES:
NA.22
Assay
97%
form
solid
reaction suitability
reagent type: reductant
mp
189-191 °C (lit.)
SMILES string
B.c1ccc(cc1)P(c2ccccc2)c3ccccc3
InChI
1S/C18H15P.BH3/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h1-15H;1H3
InChI key
CHVBILDTVBDARQ-UHFFFAOYSA-N
Application
Reactant for:
- C-P cross coupling with aryl iodides
- Synthesis of N-heterocyclic carbene borane complexes via Lewis base exchange
- Catalyst-free alcoholysis to deprotect phosphane-boranes
- Undergoing heterolytic activation
- Deprotection via reactions with resin-supported amines
- Insertion of overcrowded silylene into hydroboranes
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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