242373
Methyl 3-bromopropionate
97%
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About This Item
Linear Formula:
BrCH2CH2COOCH3
CAS Number:
Molecular Weight:
167.00
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
222-247-5
Beilstein/REAXYS Number:
1742949
MDL number:
Assay:
97%
InChI key
KQEVIFKPZOGBMZ-UHFFFAOYSA-N
InChI
1S/C4H7BrO2/c1-7-4(6)2-3-5/h2-3H2,1H3
SMILES string
COC(=O)CCBr
assay
97%
Quality Level
refractive index
n20/D 1.458 (lit.)
bp
64-66 °C/18 mmHg (lit.)
density
1.53 g/mL at 25 °C (lit.)
functional group
bromo, ester
Related Categories
Application
Methyl 3-bromopropionate was used in the synthesis of spiroanellated γ-lactones, pinacols and unprecedented 3-(1-hydroxycycloalkyl)-l-oxaspiro[n,m]alkan-2-ones.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
167.0 °F - closed cup
flash_point_c
75 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Samarium diiodide promoted spirolactonization of cycloalkanones.
Hua Z, et al.
Tetrahedron, 47(34), 7037-7044 (1991)
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