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Merck
CN

242373

Methyl 3-bromopropionate

97%

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About This Item

Linear Formula:
BrCH2CH2COOCH3
CAS Number:
3395-91-3
Molecular Weight:
167.00
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24854554
EC Number:
222-247-5
Beilstein/REAXYS Number:
1742949
MDL number:
MFCD00000250

Key Documents

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Product Name

Methyl 3-bromopropionate, 97%

InChI key

KQEVIFKPZOGBMZ-UHFFFAOYSA-N

InChI

1S/C4H7BrO2/c1-7-4(6)2-3-5/h2-3H2,1H3

SMILES string

COC(=O)CCBr

assay

97%

refractive index

n20/D 1.458 (lit.)

bp

64-66 °C/18 mmHg (lit.)

density

1.53 g/mL at 25 °C (lit.)

functional group

bromo
ester

Quality Level

200

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Application

Methyl 3-bromopropionate was used in the synthesis of spiroanellated γ-lactones, pinacols and unprecedented 3-(1-hydroxycycloalkyl)-l-oxaspiro[n,m]alkan-2-ones.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

167.0 °F - closed cup

flash_point_c

75 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
BCCK5410
BCCG8157
BCCF6032
BCCC8135
BCBP9200V

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Samarium diiodide promoted spirolactonization of cycloalkanones.
Hua Z, et al.
Tetrahedron, 47(34), 7037-7044 (1991)

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