238287
1-Iodohexane
contains copper as stabilizer, ≥98%
Synonym(s):
Hexyl iodide
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About This Item
Linear Formula:
CH3(CH2)5I
CAS Number:
Molecular Weight:
212.07
Beilstein:
505971
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Quality Level
Assay
≥98%
form
liquid
contains
copper as stabilizer
refractive index
n20/D 1.492 (lit.)
bp
179-180 °C (lit.)
density
1.437 g/mL at 25 °C (lit.)
functional group
alkyl halide
iodo
SMILES string
CCCCCCI
InChI
1S/C6H13I/c1-2-3-4-5-6-7/h2-6H2,1H3
InChI key
ANOOTOPTCJRUPK-UHFFFAOYSA-N
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General description
1-Iodohexane undergoes palladium-catalyzed cross-coupling reaction with 9-octyl-9-borabicyclo[3.3.l]nonane to give tetradecane. Thermal reactions of 1-iodohexane on Ni (100) single crystal surfaces has been studied using temperature-programmed desorption and X-ray photoelectron spectroscopy.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
141.8 °F - closed cup
Flash Point(C)
61 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Thermal Reactions of Alkyl Iodides on Ni (100) Single Crystal Surfaces.
Tjandra S and Zaera F.
Journal of the American Chemical Society, 117(38), 9749-9755 (1995)
Palladium-catalyzed carbonylative cross-coupling reaction of iodoalkanes with 9-alkyl-9-BBN derivatives. A direct and selective synthesis of ketones.
Ishiyama T and Miyaura N.
Tetrahedron Letters, 32(47), 6923-6926 (1991)
Martha Kafetzi et al.
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Barbara Nozière et al.
Angewandte Chemie (International ed. in English), 58(39), 13976-13982 (2019-07-31)
The autoxidation of organic peroxy radicals (RO2 ) into hydroperoxy-alkyl radicals (QOOH), then hydroperoxy-peroxy radicals (HOOQO2 ) is now considered to be important in the Earth's atmosphere. To avoid mechanistic uncertainties these reactions are best studied by monitoring the radicals.
Alexa Schmitz et al.
ChemistryOpen, 10(2), 153-163 (2020-12-24)
S-alkyltetrahydrothiophenium, [Cn THT]+ bis(trifluorosulfonyl)imide, [NTf2 ]- room temperature ionic liquids (ILs) and tetraphenylborate, [BPh4 ]- salts with alkyl chain lengths from C4 to C10 have been prepared. The ILs and salts were characterized and their purity verified by 1 H-
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