236616
1,2,4,5-Tetrakis(bromomethyl)benzene
95%
Synonym(s):
α,α′,α′′,α′′′-Tetrabromodurene
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About This Item
Linear Formula:
C6H2(CH2Br)4
CAS Number:
Molecular Weight:
449.80
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
95%
Form:
solid
InChI
1S/C10H10Br4/c11-3-7-1-8(4-12)10(6-14)2-9(7)5-13/h1-2H,3-6H2
SMILES string
BrCc1cc(CBr)c(CBr)cc1CBr
InChI key
UTXIKCCNBUIWPT-UHFFFAOYSA-N
assay
95%
form
solid
mp
159-161 °C (lit.)
functional group
bromo
Quality Level
Related Categories
Application
1,2,4,5-Tetrakis(bromomethyl)benzene has been used in the synthesis of:
- tetrapodal imidazolium ligands as their PF6− salts
- 6,7-bis(bromomethyl)-2,11,18,21,24-pentaoxatetracyclo[23.4. 0.04,9.012,17]nonacosa-1(25),4(9),5,7,12 (17),13,15,26,28-nonaene
- conformationally constrained cyclic α-amino acid derivatives
- thiacyclophanes
- dendrimeric organoplatinum complexes
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Canadian Journal of Chemistry, 72, 1728-1728 (1994)
Journal of the Chemical Society. Perkin Transactions 1, 1883-1883 (1994)
Journal of the Chemical Society. Chemical Communications, 1895-1895 (1994)
B Nisar Ahamed et al.
Inorganic chemistry, 52(8), 4269-4276 (2013-03-26)
Tetrapodal imidazolium ligands L(1)-L(3) as their PF6(-) salts are synthesized in good yields by reacting 1,2,4,5-tetrakis(bromomethyl)benzene with N-methylimidazole, N-benzylimidazole, and N-ethylimidazole, respectively. Single-crystal X-ray diffraction studies of L(1)·4PF6, L(2)·4PF6, and L(3)·4PF6 show the chair conformation of the tetrapodal imidazoliums (L(1)-L(3))
W Sim et al.
Acta crystallographica. Section C, Crystal structure communications, 57(Pt 3), 293-294 (2001-03-16)
The 17-crown-5 unit, C(26)H(26)Br(2)O(5), consisting of a 1,2-bis(bromomethyl) group, three benzo groups and diethylene glycol, was prepared from the reaction of 1,2,4,5-tetrakis(bromomethyl)benzene and bis-phenol in the presence of sodium hydride as a base. This molecule seems to offer an internal
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